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Literature summary extracted from

  • Pirrung, M.C.
    Ethylene biosynthesis from 1-aminocyclopropanecarboxylic acid (1999), Acc. Chem. Res., 32, 711-718.
No PubMed abstract available

Activating Compound

EC Number Activating Compound Comment Organism Structure
1.14.17.4 CO2
-
 Vigna radiata
1.14.17.4 CO2
-
 Solanum lycopersicum
1.14.17.4 CO2
-
 Cucumis melo
1.14.17.4 CO2
-
 Malus domestica

Inhibitors

EC Number Inhibitors Comment Organism Structure
1.14.17.4 cyclopropyl-1-aminocyclopropane-1-carboxylate mechanism-based suicide activator Cucumis melo
1.14.17.4 cyclopropyl-1-aminocyclopropane-1-carboxylate mechanism-based suicide activator Malus domestica
1.14.17.4 cyclopropyl-1-aminocyclopropane-1-carboxylate mechanism-based suicide activator Vigna radiata

Metals/Ions

EC Number Metals/Ions Comment Organism Structure
1.14.17.4 Fe2+
-
 Vigna radiata
1.14.17.4 Fe2+
-
 Solanum lycopersicum
1.14.17.4 Fe2+
-
 Cucumis melo
1.14.17.4 Fe2+
-
 Malus domestica

Natural Substrates/ Products (Substrates)

EC Number Natural Substrates Organism Comment (Nat. Sub.) Natural Products Comment (Nat. Pro.) Rev. Reac.
1.14.17.4 1-aminocyclopropane-1-carboxylate + ascorbate + O2 Vicia sp.
-
 ethylene + cyanide + dehydroascorbate + CO2 + H2O
-
 ?
1.14.17.4 1-aminocyclopropane-1-carboxylate + ascorbate + O2 Vigna radiata biosynthesis of plant signalling molecule ethylene ethylene + cyanide + dehydroascorbate + CO2 + H2O
-
 ?
1.14.17.4 1-aminocyclopropane-1-carboxylate + ascorbate + O2 Solanum lycopersicum biosynthesis of plant signalling molecule ethylene ethylene + cyanide + dehydroascorbate + CO2 + H2O
-
 ?
1.14.17.4 1-aminocyclopropane-1-carboxylate + ascorbate + O2 Cucumis melo biosynthesis of plant signalling molecule ethylene ethylene + cyanide + dehydroascorbate + CO2 + H2O
-
 ?
1.14.17.4 1-aminocyclopropane-1-carboxylate + ascorbate + O2 Malus domestica biosynthesis of plant signalling molecule ethylene ethylene + cyanide + dehydroascorbate + CO2 + H2O
-
 ?

Organism

EC Number Organism UniProt Comment Textmining
1.14.17.4 Cucumis melo
-
 cantaloupe
-
1.14.17.4 Malus domestica
-
-
-
1.14.17.4 Solanum lycopersicum
-
-
-
1.14.17.4 Vicia sp.
-
 vetch
-
1.14.17.4 Vigna radiata
-
-
-

Reaction

EC Number Reaction Comment Organism Reaction ID
1.14.17.4 1-aminocyclopropane-1-carboxylate + ascorbate + O2 = ethene + cyanide + dehydroascorbate + CO2 + 2 H2O catalytic mechanism Vigna radiata
a
1.14.17.4 1-aminocyclopropane-1-carboxylate + ascorbate + O2 = ethene + cyanide + dehydroascorbate + CO2 + 2 H2O catalytic mechanism Solanum lycopersicum
a
1.14.17.4 1-aminocyclopropane-1-carboxylate + ascorbate + O2 = ethene + cyanide + dehydroascorbate + CO2 + 2 H2O catalytic mechanism Cucumis melo
a
1.14.17.4 1-aminocyclopropane-1-carboxylate + ascorbate + O2 = ethene + cyanide + dehydroascorbate + CO2 + 2 H2O catalytic mechanism Malus domestica
a

Substrates and Products (Substrate)

EC Number Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
1.14.17.4 1-amino-2-ethylcyclopropane-1-carboxylate + L-ascorbate + O2
-
 Solanum lycopersicum 1-butene + cyanide + dehydroascorbate + CO2 + H2O
-
 ?
1.14.17.4 1-amino-2-ethylcyclopropane-1-carboxylate + L-ascorbate + O2 stereoselectivity Vigna radiata 1-butene + cyanide + dehydroascorbate + CO2 + H2O
-
 ?
1.14.17.4 1-amino-2-ethylcyclopropane-1-carboxylate + L-ascorbate + O2 stereoselectivity Cucumis melo 1-butene + cyanide + dehydroascorbate + CO2 + H2O
-
 ?
1.14.17.4 1-amino-2-ethylcyclopropane-1-carboxylate + L-ascorbate + O2 stereoselectivity Malus domestica 1-butene + cyanide + dehydroascorbate + CO2 + H2O
-
 ?
1.14.17.4 1-amino-2-ethylcyclopropane-1-carboxylate + L-ascorbate + O2 stereoselectivity Vicia sp. 1-butene + cyanide + dehydroascorbate + CO2 + H2O
-
 ?
1.14.17.4 1-amino-2-ethylcyclopropane-1-carboxylate + L-ascorbate + O2 i.e. allo-coronamic acid Vigna radiata 1-butene + cyanide + dehydroascorbate + CO2 + H2O
-
 ?
1.14.17.4 1-amino-2-ethylcyclopropane-1-carboxylate + L-ascorbate + O2 i.e. allo-coronamic acid Cucumis melo 1-butene + cyanide + dehydroascorbate + CO2 + H2O
-
 ?
1.14.17.4 1-amino-2-ethylcyclopropane-1-carboxylate + L-ascorbate + O2 i.e. allo-coronamic acid Malus domestica 1-butene + cyanide + dehydroascorbate + CO2 + H2O
-
 ?
1.14.17.4 1-amino-2-ethylcyclopropane-1-carboxylate + L-ascorbate + O2 i.e. allo-coronamic acid Vicia sp. 1-butene + cyanide + dehydroascorbate + CO2 + H2O
-
 ?
1.14.17.4 1-amino-2-methylcyclopropane-1-carboxylate + L-ascorbate + O2
-
 Solanum lycopersicum ?
-
 ?
1.14.17.4 1-amino-2-methylcyclopropane-1-carboxylate + L-ascorbate + O2 stereoselectivity Vigna radiata ?
-
 ?
1.14.17.4 1-amino-2-methylcyclopropane-1-carboxylate + L-ascorbate + O2 stereoselectivity Cucumis melo ?
-
 ?
1.14.17.4 1-amino-2-methylcyclopropane-1-carboxylate + L-ascorbate + O2 stereoselectivity Malus domestica ?
-
 ?
1.14.17.4 1-amino-2-methylcyclopropane-1-carboxylate + L-ascorbate + O2 stereoselectivity Vicia sp. ?
-
 ?
1.14.17.4 1-amino-2-methylcyclopropane-1-carboxylate + L-ascorbate + O2 prefers mixture of 1R,2S-amino-2-methylcyclopropane-1-carboxylate Vigna radiata ?
-
 ?
1.14.17.4 1-amino-2-methylcyclopropane-1-carboxylate + L-ascorbate + O2 prefers mixture of 1R,2S-amino-2-methylcyclopropane-1-carboxylate Cucumis melo ?
-
 ?
1.14.17.4 1-amino-2-methylcyclopropane-1-carboxylate + L-ascorbate + O2 prefers mixture of 1R,2S-amino-2-methylcyclopropane-1-carboxylate Malus domestica ?
-
 ?
1.14.17.4 1-amino-2-methylcyclopropane-1-carboxylate + L-ascorbate + O2 prefers mixture of 1R,2S-amino-2-methylcyclopropane-1-carboxylate Vicia sp. ?
-
 ?
1.14.17.4 1-aminocyclopropane-1-carboxylate + ascorbate + O2
-
 Vicia sp. ethylene + cyanide + dehydroascorbate + CO2 + H2O
-
 ?
1.14.17.4 1-aminocyclopropane-1-carboxylate + ascorbate + O2 biosynthesis of plant signalling molecule ethylene Vigna radiata ethylene + cyanide + dehydroascorbate + CO2 + H2O
-
 ?
1.14.17.4 1-aminocyclopropane-1-carboxylate + ascorbate + O2 biosynthesis of plant signalling molecule ethylene Solanum lycopersicum ethylene + cyanide + dehydroascorbate + CO2 + H2O
-
 ?
1.14.17.4 1-aminocyclopropane-1-carboxylate + ascorbate + O2 biosynthesis of plant signalling molecule ethylene Cucumis melo ethylene + cyanide + dehydroascorbate + CO2 + H2O
-
 ?
1.14.17.4 1-aminocyclopropane-1-carboxylate + ascorbate + O2 biosynthesis of plant signalling molecule ethylene Malus domestica ethylene + cyanide + dehydroascorbate + CO2 + H2O
-
 ?
1.14.17.4 1-aminocyclopropane-1-carboxylate + L-ascorbate + O2 stereoselectivity Vigna radiata ethylene + cyanide + dehydroascorbate + CO2 + H2O
-
 ?
1.14.17.4 1-aminocyclopropane-1-carboxylate + L-ascorbate + O2 stereoselectivity Cucumis melo ethylene + cyanide + dehydroascorbate + CO2 + H2O
-
 ?
1.14.17.4 1-aminocyclopropane-1-carboxylate + L-ascorbate + O2 stereoselectivity Malus domestica ethylene + cyanide + dehydroascorbate + CO2 + H2O
-
 ?
1.14.17.4 1-aminocyclopropane-1-carboxylate + L-ascorbate + O2 i.e. ACC Vigna radiata ethylene + cyanide + dehydroascorbate + CO2 + H2O
-
 ?
1.14.17.4 1-aminocyclopropane-1-carboxylate + L-ascorbate + O2 i.e. ACC Solanum lycopersicum ethylene + cyanide + dehydroascorbate + CO2 + H2O
-
 ?
1.14.17.4 1-aminocyclopropane-1-carboxylate + L-ascorbate + O2 i.e. ACC Cucumis melo ethylene + cyanide + dehydroascorbate + CO2 + H2O
-
 ?
1.14.17.4 1-aminocyclopropane-1-carboxylate + L-ascorbate + O2 i.e. ACC Malus domestica ethylene + cyanide + dehydroascorbate + CO2 + H2O
-
 ?
1.14.17.4 1-aminocyclopropane-1-carboxylate + L-ascorbate + O2 i.e. ACC Vicia sp. ethylene + cyanide + dehydroascorbate + CO2 + H2O
-
 ?