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Literature summary extracted from

  • Beecher, J.; Grogan, G.; Roberts, S.; Willetts, A.
    Enantioselective oxidations by the diketocamphane monooxygenase isoenzymes from Pseudomonas putida (1996), Biotechnol. Lett., 18, 571-576.
No PubMed abstract available

Natural Substrates/ Products (Substrates)

EC Number Natural Substrates Organism Comment (Nat. Sub.) Natural Products Comment (Nat. Pro.) Rev. Reac.
1.14.14.108 (+)-bornane-2,5-dione + FMNH2 + O2 Pseudomonas putida inducible by growth on (+)-camphor ?
-
 ?
1.14.14.108 (+)-bornane-2,5-dione + FMNH2 + O2 Pseudomonas putida NCIMB 10007 inducible by growth on (+)-camphor ?
-
 ?
1.14.14.155 (-)-bornane-2,5-dione + FMNH2 + O2 Pseudomonas putida inducible by growth on (+)-camphor ?
-
 ?
1.14.14.155 (-)-bornane-2,5-dione + FMNH2 + O2 Pseudomonas putida NCIMB 10007 inducible by growth on (+)-camphor ?
-
 ?

Organism

EC Number Organism UniProt Comment Textmining
1.14.14.108 Pseudomonas putida
-
-
-
1.14.14.108 Pseudomonas putida
-
 2 isozymes termed 2,5-diketocamphane-1,2-monooxygenase and 3,6-diketocamphane-1,6-monooxygenase
-
1.14.14.108 Pseudomonas putida NCIMB 10007
-
-
-
1.14.14.155 Pseudomonas putida
-
-
-
1.14.14.155 Pseudomonas putida
-
 2 isozymes termed 2,5-diketocamphane-1,2-monooxygenase and 3,6-diketocamphane-1,6-monooxygenase
-
1.14.14.155 Pseudomonas putida NCIMB 10007
-
-
-

Substrates and Products (Substrate)

EC Number Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
1.14.14.108 (+)-bornane-2,5-dione + FMNH2 + O2 i.e. 2,5-diketocamphane Pseudomonas putida 3,4,4-trimethyl-5-carboxy-methyl-DELTA2-cyclopentenone + FMN + H2O
-
 ?
1.14.14.108 (+)-bornane-2,5-dione + FMNH2 + O2 i.e. 2,5-diketocamphane Pseudomonas putida NCIMB 10007 3,4,4-trimethyl-5-carboxy-methyl-DELTA2-cyclopentenone + FMN + H2O
-
 ?
1.14.14.108 (+)-bornane-2,5-dione + FMNH2 + O2 inducible by growth on (+)-camphor Pseudomonas putida ?
-
 ?
1.14.14.108 (+)-bornane-2,5-dione + FMNH2 + O2 inducible by growth on (+)-camphor Pseudomonas putida NCIMB 10007 ?
-
 ?
1.14.14.108 additional information several sulfides and bicyclo[3,2,0]hept-2-en-6-one are enantioselectively oxidized to the corresponding sulfoxides and oxa lactones, respectively Pseudomonas putida ?
-
 ?
1.14.14.108 additional information several sulfides and bicyclo[3,2,0]hept-2-en-6-one are enantioselectively oxidized to the corresponding sulfoxides and oxa lactones, respectively Pseudomonas putida NCIMB 10007 ?
-
 ?
1.14.14.155 (-)-bornane-2,5-dione + FMNH2 + O2 6-dione i.e. 3,6-diketocamphane Pseudomonas putida 1,8,8-trimethyl-2-oxabicyclo[3.2.1]octane-3,6-dione + FMN + H2O
-
 ?
1.14.14.155 (-)-bornane-2,5-dione + FMNH2 + O2 6-dione i.e. 3,6-diketocamphane Pseudomonas putida NCIMB 10007 1,8,8-trimethyl-2-oxabicyclo[3.2.1]octane-3,6-dione + FMN + H2O
-
 ?
1.14.14.155 (-)-bornane-2,5-dione + FMNH2 + O2 inducible by growth on (+)-camphor Pseudomonas putida ?
-
 ?
1.14.14.155 (-)-bornane-2,5-dione + FMNH2 + O2 inducible by growth on (+)-camphor Pseudomonas putida NCIMB 10007 ?
-
 ?

Synonyms

EC Number Synonyms Comment Organism
1.14.14.108 2,5-diketocamphane 1,2-monooxygenase higher regio- and enatioselectivity than isoform 3,6-diketocamphane-1,6-monooxygenase Pseudomonas putida
1.14.14.108 3,6-diketocamphane 1,6-monooxygenase
-
 Pseudomonas putida
1.14.14.155 3,6-diketocamphane 1,6-monooxygenase isoform, which is probably a different enzyme Pseudomonas putida
1.14.14.155 More lower regio- and enatioselectivity than isoform 2,5-diketocamphane-1,2-monooxygenase Pseudomonas putida