Literature summary extracted from

Krieger, C.J.; Rosebooms, W.; Albrachts, P.J.; Spormann, A.M.
A stable organic free radical in anaerobic benzylsuccinate synthase of Azoarcus sp. strain T (2001), J. Biol. Chem., 276, 12924-12927.

Natural Substrates/ Products (Substrates)

EC Number	Natural Substrates	Organism	Comment (Nat. Sub.)	Natural Products	Comment (Nat. Pro.)	Rev.	Reac.
4.1.99.11	toluene + fumarate	Azoarcus sp.	-	benzylsuccinate	-	?
4.1.99.11	toluene + fumarate	Azoarcus sp. T	-	benzylsuccinate	-	?

Organism

EC Number	Organism	UniProt	Comment	Textmining
4.1.99.11	Azoarcus sp.	-	-	-
4.1.99.11	Azoarcus sp. T	-	-	-

Reaction

EC Number	Reaction	Comment	Organism	Reaction ID
4.1.99.11	benzylsuccinate = toluene + fumarate	stereospecific radical addition of toluene to fumarate, enzyme carries a stable organic free radical, most probably located on glycine residue 828	Azoarcus sp.	a

Substrates and Products (Substrate)

EC Number	Substrates	Comment Substrates	Organism	Products	Comment (Products)	Rev.	Reac.
4.1.99.11	toluene + fumarate	-	Azoarcus sp.	benzylsuccinate	-	?
4.1.99.11	toluene + fumarate	-	Azoarcus sp. T	benzylsuccinate	-	?

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Release 2023.1 (January 2023)