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Literature summary for 5.5.1.22 extracted from

  • Croteau, R.B.; Shaskus, J.J.; Renstrom, B.; Felton, N.M.; Cane, D.E.; Saito, A.; Chang, C.
    Mechanism of the pyrophosphate migration in the enzymatic cyclization of geranyl and linalyl pyrophosphate to (+)- and (-)-bornyl pyrophosphate (1985), Biochemistry, 24, 7077-7085.
    View publication on PubMed

Natural Substrates/ Products (Substrates)

Natural Substrates Organism Comment (Nat. Sub.) Natural Products Comment (Nat. Pro.) Rev. Reac.
geranyl diphosphate Salvia officinalis
-
(-)-bornyl diphosphate i.e. (2R,4S)-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl diphosphate ?
geranyl diphosphate Tanacetum vulgare
-
(-)-bornyl diphosphate i.e. (2R,4S)-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl diphosphate ?

Organism

Organism UniProt Comment Textmining
Salvia officinalis
-
-
-
Tanacetum vulgare
-
-
-

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
(3S)-linalyl diphosphate
-
Salvia officinalis (-)-bornyl diphosphate
-
?
(3S)-linalyl diphosphate
-
Tanacetum vulgare (-)-bornyl diphosphate
-
?
geranyl diphosphate
-
Salvia officinalis (-)-bornyl diphosphate i.e. (2R,4S)-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl diphosphate ?
geranyl diphosphate
-
Tanacetum vulgare (-)-bornyl diphosphate i.e. (2R,4S)-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl diphosphate ?