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Literature summary for 5.3.3.10 extracted from
- Stereochemical studies of 5-(carboxymethyl)-2-hydroxymuconate isomerase and 5-(carboxymethyl)-2-oxo-3-hexene-1,6-dioate decarboxylase from Escherichia coli C: mechanistic and evolutionary implications (1995), J. Am. Chem. Soc., 117, 8719-8726.
No PubMed abstract available
Natural Substrates/ Products (Substrates)
| Natural Substrates | Organism | Comment (Nat. Sub.) | Natural Products | Comment (Nat. Pro.) | Rev. | Reac. |
|---|---|---|---|---|---|---|
| 5-carboxymethyl-2-hydroxymuconate | Escherichia coli | reaction in homoprotocatechuate meta-fission pathway | ? | - |
? |  |
Organism
| Organism | UniProt | Comment | Textmining |
|---|---|---|---|
| Escherichia coli | - |
- |
- |
Reaction
| Reaction | Comment | Organism | Reaction ID |
|---|---|---|---|
| 5-carboxymethyl-2-hydroxymuconate = (3E,5R)-5-carboxy-2-oxohept-3-enedioate | mechanism | Escherichia coli |
Substrates and Products (Substrate)
| Substrates | Comment Substrates | Organism | Products | Comment (Products) | Rev. | Reac. |
|---|---|---|---|---|---|---|
| 5-carboxymethyl-2-hydroxymuconate | - |
Escherichia coli | 5-carboxy-2-oxohept-3-enedioate | R-configuration at C-5 | ? | |
| 5-carboxymethyl-2-hydroxymuconate | reaction in homoprotocatechuate meta-fission pathway | Escherichia coli | ? | - |
? | |
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