Literature summary for 5.3.2.6 extracted from

Poddar, H.; Rahimi, M.; Geertsema, E.M.; Thunnissen, A.M.; Poelarends, G.J.
Evidence for the formation of an enamine species during aldol and Michael-type addition reactions promiscuously catalyzed by 4-oxalocrotonate tautomerase (2015), ChemBioChem, 16, 738-741 .

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Inhibitors

Inhibitors	Comment	Organism	Structure
2-Oxo-3-pentynoate	-	Pseudomonas putida

Natural Substrates/ Products (Substrates)

Natural Substrates	Organism	Comment (Nat. Sub.)	Natural Products	Comment (Nat. Pro.)	Rev.	Reac.
(2Z,4E)-2-hydroxyhexa-2,4-dienedioate	Pseudomonas putida	-	(3E)-2-oxohex-3-enedioate	-	r

Organism

Organism	UniProt	Comment	Textmining
Pseudomonas putida	Q01468	-	-

Substrates and Products (Substrate)

Substrates	Comment Substrates	Organism	Products	Comment (Products)	Rev.	Reac.
(2Z,4E)-2-hydroxyhexa-2,4-dienedioate	-	Pseudomonas putida	(3E)-2-oxohex-3-enedioate	-	r
acetaldehyde + benzaldehyde	-	Pseudomonas putida	cinnamaldehyde	-	r

Synonyms

Synonyms	Comment	Organism
4-OT	-	Pseudomonas putida
4-oxalocrotonate tautomerase	-	Pseudomonas putida

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Release 2023.1 (January 2023)