Literature summary for 5.3.2.6 extracted from

Stack, T.M.M.; Li, W.; Johnson, W.H.; Zhang, Y.J.; Whitman, C.P.
Inactivation of 4-oxalocrotonate tautomerase by 5-halo-2-hydroxy-2,4-pentadienoates (2018), Biochemistry, 57, 1012-1021 .

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Inhibitors

Inhibitors	Comment	Organism	Structure
(2E,4Z)-2-bromo-5-hydroxyhexa-2,4-dienedioic acid	-	Leptothrix cholodnii
(2E,4Z)-2-bromo-5-hydroxyhexa-2,4-dienedioic acid	-	Pseudomonas putida
(2E,4Z)-2-chloro-5-hydroxyhexa-2,4-dienedioic acid	-	Leptothrix cholodnii
(2E,4Z)-2-chloro-5-hydroxyhexa-2,4-dienedioic acid	-	Pseudomonas putida
(2E,4Z)-2-fluoro-5-hydroxyhexa-2,4-dienedioic acid	-	Leptothrix cholodnii
(2E,4Z)-2-fluoro-5-hydroxyhexa-2,4-dienedioic acid	-	Pseudomonas putida
(2Z,4E)-5-bromo-2-hydroxypenta-2,4-dienoic acid	-	Leptothrix cholodnii
(2Z,4E)-5-bromo-2-hydroxypenta-2,4-dienoic acid	-	Pseudomonas putida
(2Z,4E)-5-chloro-2-hydroxypenta-2,4-dienoic acid	-	Leptothrix cholodnii
(2Z,4E)-5-chloro-2-hydroxypenta-2,4-dienoic acid	-	Pseudomonas putida
(2Z,4E)-5-fluoro-2-hydroxypenta-2,4-dienoic acid	-	Leptothrix cholodnii
(2Z,4E)-5-fluoro-2-hydroxypenta-2,4-dienoic acid	-	Pseudomonas putida
(3Z)-5-bromo-2-oxopent-3-enoic acid	-	Leptothrix cholodnii
(3Z)-5-bromo-2-oxopent-3-enoic acid	-	Pseudomonas putida
(3Z)-5-chloro-2-oxopent-3-enoic acid	-	Leptothrix cholodnii
(3Z)-5-chloro-2-oxopent-3-enoic acid	-	Pseudomonas putida
(3Z)-5-fluoro-2-oxopent-3-enoic acid	-	Leptothrix cholodnii
(3Z)-5-fluoro-2-oxopent-3-enoic acid	-	Pseudomonas putida

Natural Substrates/ Products (Substrates)

Natural Substrates	Organism	Comment (Nat. Sub.)	Natural Products	Comment (Nat. Pro.)	Rev.	Reac.
(2Z,4E)-2-hydroxyhexa-2,4-dienedioate	Leptothrix cholodnii	-	(3E)-2-oxohex-3-enedioate	-	r
(2Z,4E)-2-hydroxyhexa-2,4-dienedioate	Pseudomonas putida	-	(3E)-2-oxohex-3-enedioate	-	r
(2Z,4E)-2-hydroxyhexa-2,4-dienedioate	Leptothrix cholodnii SP-6	-	(3E)-2-oxohex-3-enedioate	-	r

Organism

Organism	UniProt	Comment	Textmining
Leptothrix cholodnii	-	-	-
Leptothrix cholodnii SP-6	-	-	-
Pseudomonas putida	Q01468	-	-

Purification (Commentary)

Purification (Comment)	Organism
-	Leptothrix cholodnii
-	Pseudomonas putida

Substrates and Products (Substrate)

Substrates	Comment Substrates	Organism	Products	Comment (Products)	Rev.	Reac.
(2Z,4E)-2-hydroxyhexa-2,4-dienedioate	-	Leptothrix cholodnii	(3E)-2-oxohex-3-enedioate	-	r
(2Z,4E)-2-hydroxyhexa-2,4-dienedioate	-	Pseudomonas putida	(3E)-2-oxohex-3-enedioate	-	r
(2Z,4E)-2-hydroxyhexa-2,4-dienedioate	-	Leptothrix cholodnii SP-6	(3E)-2-oxohex-3-enedioate	-	r

Subunits

Subunits	Comment	Organism
?	x * 6812, electrospray ionization mass spectrometry	Pseudomonas putida

Synonyms

Synonyms	Comment	Organism
4-OT	-	Leptothrix cholodnii
4-OT	-	Pseudomonas putida
4-oxalocrotonate tautomerase	-	Leptothrix cholodnii
4-oxalocrotonate tautomerase	-	Pseudomonas putida

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Release 2023.1 (January 2023)