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Literature summary for 4.2.3.7 extracted from

  • Cane, D.E.; Abell, C.; Lattman, R.; Kane, C.T.; Hubbard, B.R.; Harrison, P.H.M.
    Pentalenene biosynthesis and the enzymatic cyclisation of farnesyl pyrophosphate. Anti stereochemistry in a biological SE reaction (1988), J. Am. Chem. Soc., 110, 4081-4082.
No PubMed abstract available

Natural Substrates/ Products (Substrates)

Natural Substrates Organism Comment (Nat. Sub.) Natural Products Comment (Nat. Pro.) Rev. Reac.
farnesyl diphosphate Streptomyces sp.
-
pentalenene + diphosphate
-
?
farnesyl diphosphate Streptomyces sp. UC5319
-
pentalenene + diphosphate
-
?

Organism

Organism UniProt Comment Textmining
Streptomyces sp.
-
UC5319
-
Streptomyces sp. UC5319
-
UC5319
-

Reaction

Reaction Comment Organism Reaction ID
(2E,6E)-farnesyl diphosphate = pentalenene + diphosphate mechanism Streptomyces sp.
(2E,6E)-farnesyl diphosphate = pentalenene + diphosphate stereochemistry Streptomyces sp.

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
farnesyl diphosphate
-
Streptomyces sp. pentalenene + diphosphate
-
?
farnesyl diphosphate trans,trans Streptomyces sp. pentalenene + diphosphate
-
?
farnesyl diphosphate
-
Streptomyces sp. UC5319 pentalenene + diphosphate
-
?
farnesyl diphosphate trans,trans Streptomyces sp. UC5319 pentalenene + diphosphate
-
?