Natural Substrates | Organism | Comment (Nat. Sub.) | Natural Products | Comment (Nat. Pro.) | Rev. | Reac. |
---|---|---|---|---|---|---|
(2Z, 6E)-farnesyl diphosphate | Heteroscyphus planus | - |
(-)-gamma-cadinene + diphosphate | formation of gamma-cadinene involves a 1,3-hydride shift. (-)-gamma-Cadinene is directly formed from 2Z,6E-farnesyl diphosphate by intramolecular electrophilic attack of the primary carbocation on the C-10 position of farnesyl diphosphate. Second product: (+)-germacrene D | ? |
Organism | UniProt | Comment | Textmining |
---|---|---|---|
Heteroscyphus planus | - |
- |
- |
Purification (Comment) | Organism |
---|---|
partial | Heteroscyphus planus |
Specific Activity Minimum [µmol/min/mg] | Specific Activity Maximum [µmol/min/mg] | Comment | Organism |
---|---|---|---|
268 | - |
pH 7.5, 30°C | Heteroscyphus planus |
Substrates | Comment Substrates | Organism | Products | Comment (Products) | Rev. | Reac. |
---|---|---|---|---|---|---|
(2Z, 6E)-farnesyl diphosphate | - |
Heteroscyphus planus | (-)-gamma-cadinene + diphosphate | formation of gamma-cadinene involves a 1,3-hydride shift. (-)-gamma-Cadinene is directly formed from 2Z,6E-farnesyl diphosphate by intramolecular electrophilic attack of the primary carbocation on the C-10 position of farnesyl diphosphate. Second product: (+)-germacrene D | ? |