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Literature summary for 4.2.3.62 extracted from

  • Nabeta, K.; Fujita, M.; Komuro, K.; Katayama, K.; Takasawa, T.
    In vitro biosynthesis of cadinanes by cell-free extracts of cultured cells of Heteroscyphus planus (1997), J. Chem. Soc., 1, 2065-2070.
No PubMed abstract available

Natural Substrates/ Products (Substrates)

Natural Substrates Organism Comment (Nat. Sub.) Natural Products Comment (Nat. Pro.) Rev. Reac.
(2Z, 6E)-farnesyl diphosphate Heteroscyphus planus
-
(-)-gamma-cadinene + diphosphate formation of gamma-cadinene involves a 1,3-hydride shift. (-)-gamma-Cadinene is directly formed from 2Z,6E-farnesyl diphosphate by intramolecular electrophilic attack of the primary carbocation on the C-10 position of farnesyl diphosphate. Second product: (+)-germacrene D ?

Organism

Organism UniProt Comment Textmining
Heteroscyphus planus
-
-
-

Purification (Commentary)

Purification (Comment) Organism
partial Heteroscyphus planus

Specific Activity [micromol/min/mg]

Specific Activity Minimum [µmol/min/mg] Specific Activity Maximum [µmol/min/mg] Comment Organism
268
-
pH 7.5, 30°C Heteroscyphus planus

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
(2Z, 6E)-farnesyl diphosphate
-
Heteroscyphus planus (-)-gamma-cadinene + diphosphate formation of gamma-cadinene involves a 1,3-hydride shift. (-)-gamma-Cadinene is directly formed from 2Z,6E-farnesyl diphosphate by intramolecular electrophilic attack of the primary carbocation on the C-10 position of farnesyl diphosphate. Second product: (+)-germacrene D ?