Literature summary for 4.2.3.32 extracted from

Keeling, C.I.; Madilao, L.L.; Zerbe, P.; Dullat, H.K.; Bohlmann, J.
The primary diterpene synthase products of Picea abies levopimaradiene/abietadiene synthase (PaLAS) are epimers of a thermally unstable diterpenol (2011), J. Biol. Chem., 286, 21145-21153.

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Organism

Organism	UniProt	Comment	Textmining
Picea abies	Q675L4	-	-

Substrates and Products (Substrate)

Substrates	Comment Substrates	Organism	Products	Comment (Products)	Rev.	Reac.
(+)-copalyl-diphosphate	-	Picea abies	13-hydroxy-8(14)-abietene + diphosphate	the initial products formed and released in vitro are unstable alcohols identified as epimeric thermally unstable allylic tertiary alcohols, 13-hydroxy-8(14)-abietene. The dehydration of the alcohol products, yielding the well established diterpene products levopimaradiene, abietadiene, neoabietadiene, and palustradiene, occurs due to the conditions of the GC-MS analysis typically used	?

Synonyms

Synonyms	Comment	Organism
levopimaradiene/abietadiene synthase	-	Picea abies
PaLAS	-	Picea abies

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Release 2023.1 (January 2023)