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Literature summary for 4.2.3.197 extracted from

  • Liang, J.; Liu, J.; Brown, R.; Jia, M.; Zhou, K.; Peters, R.; Wang, Q.
    Direct production of dihydroxylated sesquiterpenoids by a maize terpene synthase (2018), Plant J., 94, 847-856 .
    View publication on PubMedView publication on EuropePMC
Search for more literature for 4.2.3.197

Cloned(Commentary)

Cloned (Comment) Organism
expressed in Escherichia coli Zea mays
expressed in leaves of Nicotiana benthamiana Zea mays

Protein Variants

Protein Variants Comment Organism
F303A mutant enzyme shows predominant production of hedycarol Zea mays
Y529F while the ZmEDS:Y529F mutant produces an increased amount of hedycaryol the other products, including the sesquiterpenoid diols, are still present Zea mays

Natural Substrates/ Products (Substrates)

Natural Substrates Organism Comment (Nat. Sub.) Natural Products Comment (Nat. Pro.) Rev. Reac.
(2E,6E)-farnesyl diphosphate + 2 H2O Zea mays
-
 7-epi-ent-eudesmane-5,11-diol + diphosphate
-
 ?

Organism

Organism UniProt Comment Textmining
Zea mays
-
-
-

Source Tissue

Source Tissue Comment Organism Textmining
root ZmEDS is specifically expressed in roots Zea mays
-

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
(2E,6E)-farnesyl diphosphate + 2 H2O
-
 Zea mays 7-epi-ent-eudesmane-5,11-diol + diphosphate
-
 ?
(2E,6E)-farnesyl diphosphate + 2 H2O 7-epi-ent-eudesmane-5,11-diol i.e. (4S,4aS,6R,8aS)-6-(2-hydroxypropan-2-yl)-4,8a-dimethyldecahydronaphthalen-4a-ol Zea mays 7-epi-ent-eudesmane-5,11-diol + diphosphate
-
 ?

Synonyms

Synonyms Comment Organism
maize eudesmanediol synthase
-
 Zea mays
ZmEDS
-
 Zea mays

Expression

Organism Comment Expression
Zea mays infection with the fungal pathogen Fusarium verticillioides significantly induces accumulation of ZmEDS transcripts in roots up