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Literature summary for 4.2.3.139 extracted from

  • Yeo, Y.; Nybo, S.; Chittiboyina, A.; Weerasooriya, A.; Wang, Y.; Gongora-Castillo, E.; Vaillancourt, B.; Buell, C.; Dellapenna, D.; Celiz, M.; Daniel Jones, A.; Wurtele, E.; Ransom, N.; Dudareva, N.; Shaaban, K.; Tibrewal, N.; Chandra, S.; Smillie, T.; K
    Functional identification of valerena-1,10-diene synthase, a terpene synthase catalyzing a unique chemical cascade in the biosynthesis of biologically active sesquiterpenes in Valeriana officinalis (2013), J. Biol. Chem., 288, 3163-3173.
    View publication on PubMedView publication on EuropePMC
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Organism

Organism UniProt Comment Textmining
Valeriana officinalis L0HP52
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Source Tissue

Source Tissue Comment Organism Textmining
root mainly lateral root Valeriana officinalis
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Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
(2E,6E)-farnesyl diphosphate mechanism: C1 forms a bond with C11 of the originating farnesyl diphosphate molecule to form a caryophyllenyl carbocation followed by opening of the cyclobutyl ring to yield the desired isobutenyl side chain Valeriana officinalis valerena-4,7(11)-diene + diphosphate
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 ?
additional information poor substrate: geranyl diphosphate Valeriana officinalis ?
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Synonyms

Synonyms Comment Organism
sesquiterpene synthase 1
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 Valeriana officinalis
TPS1
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 Valeriana officinalis