Molecular Weight [Da] | Molecular Weight Maximum [Da] | Comment | Organism |
---|---|---|---|
100000 | - |
gel filtration | Salvia officinalis |
Organism | UniProt | Comment | Textmining |
---|---|---|---|
Salvia officinalis | - |
- |
- |
Purification (Comment) | Organism |
---|---|
partial | Salvia officinalis |
Source Tissue | Comment | Organism | Textmining |
---|---|---|---|
leaf | - |
Salvia officinalis | - |
Substrates | Comment Substrates | Organism | Products | Comment (Products) | Rev. | Reac. |
---|---|---|---|---|---|---|
geranyl diphosphate | - |
Salvia officinalis | (+)-alpha-pinene + diphosphate | reaction proceeds stereoselectively to (+)-borneol, which is oxidised to (+)-camphor. Configuration at C1 of geranyl pyrophosphate is retained in the enzymatic transformations. The 1-proR-hydrogen of neryl diphosphate gives rise to the exo-alpha-hydrogen of (+)-camphor, and the 1-proS-hydrogen to the endo-alpha-hydrogen, whereas the 1-proS-hydrogen of this precursor gives rise to the exo-alpha-hydrogen of the enantiomeric (-)-camphor, and the 1-proR-hydrogen to the endo-alpha-hydrogen. The configuration at C1 of neryl pyrophosphate is inverted in the cyclizations to alpha- and beta-pinene, and fully consistent with the cyclization model | ? |