KM Value [mM] | KM Value Maximum [mM] | Substrate | Comment | Organism | Structure |
---|---|---|---|---|---|
0.0021 | - |
neryl diphosphate | pH 6.5, 30°C | Salvia officinalis | |
0.003 | - |
geranyl diphosphate | pH 6.5, 30°C | Salvia officinalis | |
0.0035 | - |
(3S)-linalyl diphosphate | pH 6.5, 30°C | Salvia officinalis | |
0.0035 | - |
(3R)-linalyl diphosphate | pH 6.5, 30°C | Salvia officinalis |
Organism | UniProt | Comment | Textmining |
---|---|---|---|
Salvia officinalis | - |
- |
- |
Substrates | Comment Substrates | Organism | Products | Comment (Products) | Rev. | Reac. |
---|---|---|---|---|---|---|
(3R)-linalyl diphosphate | - |
Salvia officinalis | (-)-alpha-pinene + diphosphate | products are 17% (-)-alpha-pinene, 9% beta-pinene, 3% camphene, 28% limonene, 9% terpinolene, 23% myrcene, 3% cis-ocimene, 13% trans-ocimene | ? | |
(3S)-linalyl diphosphate | - |
Salvia officinalis | (-)-alpha-pinene + diphosphate | products are 15% (-)-alpha-pinene, 18% beta-pinene, 12% camphene, 11% limonene, 6% terpinolene, 23% myrcene, 3% cis-ocimene, 8% trans-ocimene | ? | |
geranyl diphosphate | - |
Salvia officinalis | (-)-alpha-pinene + diphosphate | products are 28% (-)-alpha-pinene, 35% beta-pinene, 24% camphene, 5% limonene, 2% terpinolene, 6% myrcene | ? | |
additional information | reaction follows a cisoid, anti-endo-pattern. In the case of geranyl diphosphate, a preassociation mechanism is suggested in which optimum folding of the terpenyl chain precedes the initial ionization step. The alternate substrates are ionized by the cyclases prior to their achieving the optimum orientation for bicyclization | Salvia officinalis | ? | - |
? | |
neryl diphosphate | - |
Salvia officinalis | (-)-alpha-pinene + diphosphate | products are 18% (-)-alpha-pinene, 18% beta-pinene, 12% camphene, 42% limonene, 9% terpinolene, 9% myrcene | ? |
Synonyms | Comment | Organism |
---|---|---|
(-)-pinene cyclase | - |
Salvia officinalis |