Literature summary for 4.2.3.10 extracted from

Croteau, R.; Satterwhite, D.M.; Wheeler, C.J.; Felton, N.M.
Biosynthesis of monoterpenes. Stereochemistry of the enzymatic cyclization of geranyl pyrophosphate to (-)-endo-fenchol (1988), J. Biol. Chem., 263, 15449-15453.

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Metals/Ions

Metals/Ions	Comment	Organism	Structure
Mn2+	Mn2+-dependent	Anethum foeniculum

Organism

Organism	UniProt	Comment	Textmining
Anethum foeniculum	-	M. var. vulgare	-

Purification (Commentary)

Purification (Comment)	Organism
partial	Anethum foeniculum

Reaction

Reaction	Comment	Organism	Reaction ID
geranyl diphosphate + H2O = (-)-endo-fenchol + diphosphate	reaction mechanism	Anethum foeniculum	a
geranyl diphosphate + H2O = (-)-endo-fenchol + diphosphate	(3R)-linalyl diphosphate is an intermediate in the reaction	Anethum foeniculum	a

Source Tissue

Source Tissue	Comment	Organism	Textmining
fruit	schizocarps	Anethum foeniculum	-

Substrates and Products (Substrate)

Substrates	Comment Substrates	Organism	Products	Comment (Products)	Rev.	Reac.
geranyl diphosphate	mechanism of the isomerization-cyclization reaction	Anethum foeniculum	(-)-endo-fenchol + diphosphate	-	?
geranyl diphosphate	stereochemistry, syn-isomerization of substrate to (3R)-linalyl diphosphate and cyclization of the latter via the anti-endo-conformer	Anethum foeniculum	(-)-endo-fenchol + diphosphate	-	?
geranyl diphosphate	(3R)-linalyl diphosphate is an intermediate in the reaction	Anethum foeniculum	(-)-endo-fenchol + diphosphate	-	?

Temperature Optimum [°C]

Temperature Optimum [°C]	Temperature Optimum Maximum [°C]	Comment	Organism
30	-	assay at	Anethum foeniculum

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Release 2023.1 (January 2023)