Application | Comment | Organism |
---|---|---|
synthesis | production of organosilicon compounds by enantioselective transcyanation. Under optimum conditions, both acetyltrimethylsilane conversion to (R)-2-trimethylsilyl-2-hydroxy-ethylcyanide and enantiomeric excess of the product are above 99%. the silicon atom in acetyltrimethylsilane has a great effect on the eaction and both the substrate conversion and the product enantiomeric excess are much higher than those in its carbon counterpart 3,3-dimethyl-2-butanone | Prunus persica |
Organism | UniProt | Comment | Textmining |
---|---|---|---|
Prunus persica | - |
- |
- |
Source Tissue | Comment | Organism | Textmining |
---|---|---|---|
seed | defatted seed meal | Prunus persica | - |
Substrates | Comment Substrates | Organism | Products | Comment (Products) | Rev. | Reac. |
---|---|---|---|---|---|---|
3,3-dimethyl-2-butanone + acetone cyanohydrin | - |
Prunus persica | 2-hydroxy-2,3,3-trimethylbutanenitrile + acetone | - |
? | |
acetyltrimethylsilane + acetone cyanohydrin | - |
Prunus persica | (R)-2-trimethylsilyl-2-hydroxy-ethylcyanide + acetone | enantioselective transcyanation. Under optimum conditions, both acetyltrimethylsilane conversion to (R)-2-trimethylsilyl-2-hydroxy-ethylcyanide and enantiomeric excess of the product are above 99%. The silicon atom in acetyltrimethylsilane has a great effect on the eaction and both the substrate conversion and the product enantiomeric excess are much higher than those in its carbon counterpart 3,3-dimethyl-2-butanone | ? |