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Literature summary for 4.1.2.23 extracted from
- Synthesis of 3-deoxy-D-manno-2-octulosonic acid (KDO) and its analogs based on KDO aldolase-catalyzed reactions (1993), J. Am. Chem. Soc., 115, 413-421.
No PubMed abstract available
Organism
| Organism | UniProt | Comment | Textmining |
|---|---|---|---|
| Microbacterium barkeri | - |
- |
- |
Reaction
| Reaction | Comment | Organism | Reaction ID |
|---|---|---|---|
| 3-deoxy-D-manno-octulosonate = pyruvate + D-arabinose | attack of pyruvate takes place on the re face of the carbonyl group of aceptor substrates | Microbacterium barkeri |
Substrates and Products (Substrate)
| Substrates | Comment Substrates | Organism | Products | Comment (Products) | Rev. | Reac. |
|---|---|---|---|---|---|---|
| 3-deoxy-D-manno-octulosonate | - |
Microbacterium barkeri | pyruvate + D-arabinose | - |
? |  |
| pyruvate + 2-deoxy-2-fluoro-D-arabinose | at 46% of the activity with D-arabinose | Microbacterium barkeri | 3,5-dideoxy-5-fluoro-alpha-D-manno-2-octulosonic acid | - |
? | |
| pyruvate + 2-deoxy-D-ribose | at 71% of the activity with D-arabinose | Microbacterium barkeri | 3,5-dideoxy-alpha-D-manno-2-octulosonic acid | - |
? | |
| pyruvate + 5-azido-2,5-dideoxy-D-ribose | at 15% of the activity with D-arabinose | Microbacterium barkeri | ? | - |
? | |
| pyruvate + D-altrose | at 25% of the activity with D-arabinose | Microbacterium barkeri | D-erythrose + D-glyceraldehyde | - |
? | |
| pyruvate + D-arabinose | - |
Microbacterium barkeri | 3-deoxy-D-manno-octulosonate | 3-deoxy-D-manno-2-octulosonate | ? | |
| pyruvate + D-erythrose | at 93% of the activity with D-arabinose | Microbacterium barkeri | ? | - |
? | |
| pyruvate + D-glyceraldehyde | at 23% of the activity with D-arabinose | Microbacterium barkeri | 2-dehydro-3-deoxy-D-galactonate | - |
? | |
| pyruvate + D-lyxose | at 35% of the activity with D-arabinose | Microbacterium barkeri | ? | - |
? | |
| pyruvate + D-ribose | at 72% of the activity with D-arabinose | Microbacterium barkeri | 3-deoxy-L-glycero-L-galacto-2-nonulosonic acid | - |
? | |
| pyruvate + D-threose | at 128% of the activity with D-arabinose | Microbacterium barkeri | ? | - |
? | |
| pyruvate + L-glyceraldehyde | at 36% of the activity with D-arabinose | Microbacterium barkeri | 2-keto-3-deoxy-L-gluconic acid | - |
? | |
| pyruvate + L-mannose | - |
Microbacterium barkeri | 3-deoxy-alpha-D-arabino-2-heptulosonic acid | - |
? | |
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