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Literature summary for 4.1.1.7 extracted from

  • Berheide, M.; Kara, S.; Liese, A.
    Reversibility of asymmetric catalyzed C-C bond formation by benzoylformate decarboxylase (2015), Catal. Sci. Technol., 5, 2418-2426 .
No PubMed abstract available

KM Value [mM]

KM Value [mM] KM Value Maximum [mM] Substrate Comment Organism Structure
62
-
(R)-2-hydroxy-1-phenylpropanone at pH 7.5 and 30°C Pseudomonas putida
62
-
(S)-2-hydroxy-1-phenylpropanone at pH 7.5 and 30°C Pseudomonas putida

Metals/Ions

Metals/Ions Comment Organism Structure
Mg2+ required Pseudomonas putida

Organism

Organism UniProt Comment Textmining
Pseudomonas putida
-
-
-

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
(R)-2-hydroxy-1-phenylpropanone + acetaldehyde
-
Pseudomonas putida ?
-
r
(S)-2-hydroxy-1-phenylpropanone + acetaldehyde
-
Pseudomonas putida ?
-
r
2 benzaldehyde
-
Pseudomonas putida (R)-benzoin
-
r
benzaldehyde + acetaldehyde
-
Pseudomonas putida (S)-2-hydroxy-1-phenylpropanone
-
r
benzoin + acetaldehyde
-
Pseudomonas putida 2-hydroxy-1-phenylpropanone
-
r

Synonyms

Synonyms Comment Organism
BFD
-
Pseudomonas putida

Cofactor

Cofactor Comment Organism Structure
thiamine diphosphate
-
Pseudomonas putida