Application | Comment | Organism |
---|---|---|
synthesis | enzyme-catalyzed synthesis of enantiomerically pure (R)-benzoin derivatives in good yield | Pseudomonas putida |
Organism | UniProt | Comment | Textmining |
---|---|---|---|
Pseudomonas putida | - |
- |
- |
Substrates | Comment Substrates | Organism | Products | Comment (Products) | Rev. | Reac. |
---|---|---|---|---|---|---|
2-fluorobenzaldehyde | carboligation | Pseudomonas putida | (R)-1,2-Bis-(2-fluoro-phenyl)-2-hydroxy-ethanone | 68% yield and more than 99% enantiomeric excess of the (R)-enantiomer | ? | |
2-furaldehyde | carboligation | Pseudomonas putida | (R)-1,2-di-furan-2-yl-2-hydroxy-ethanone | 62% yield and 94% enantiomeric excess of the (R)-enantiomer | ? | |
3-methoxybenzaldehyde | carboligation | Pseudomonas putida | (R)-2-Hydroxy-1,2-bis-(3-methoxy-phenyl)-ethanone | 18% yield and more than 99% enantiomeric excess of the (R)-enantiomer | ? | |
4-bromobenzaldehyde | carboligation | Pseudomonas putida | (R)-1,2-bis-(4-bromo-phenyl)-2-hydroxy-ethanone | 13% yield and more than 99% enantiomeric excess of the (R)-enantiomer | ? | |
4-chlorobenzaldehyde | carboligation | Pseudomonas putida | (R)-1,2-bis-(4-chloro-phenyl)-2-hydroxy-ethanone | 17% yield and more than 99% enantiomeric excess of the (R)-enantiomer | ? | |
4-fluorobenzaldehyde | carboligation | Pseudomonas putida | (R)-1,2-Bis-(4-fluoro-phenyl)-2-hydroxy-ethanone | 25% yield and more than 99% enantiomeric excess of the (R)-enantiomer | ? | |
4-methoxybenzaldehyde | carboligation | Pseudomonas putida | (R)-2-Hydroxy-1,2-bis-(4-methoxy-phenyl)-ethanone | 12% yield and more than 99% enantiomeric excess of the (R)-enantiomer | ? | |
4-methylbenzaldehyde | carboligation | Pseudomonas putida | (R)-2-Hydroxy-1,2-di-p-tolyl-ethanone | 69% yield and more than 99% enantiomeric excess of the (R)-enantiomer | ? | |
5-methyl-furan-2-carbaldehyde | carboligation | Pseudomonas putida | (R)-2-Hydroxy-1,2-bis-(5-methyl-furan-2-yl)-ethanone | 50% yield and 96% enantiomeric excess of the (R)-enantiomer | ? | |
benzaldehyde + benzaldehyde | carboligation | Pseudomonas putida | (R)-benzoin | 70% yield and more than 99% enantiomeric excess of the (R)-enantiomer | ? | |
pyridine-2-carbaldehyde | carboligation | Pseudomonas putida | (R)-2-Hydroxy-1,2-di-pyridin-2-yl-ethanone | 70% yield and 94% enantiomeric excess of the (R)-enantiomer | ? | |
thiophene-2-carbaldehyde | carboligation | Pseudomonas putida | (S)-2-Hydroxy-1,2-di-thiophen-2-yl-ethanone | 65% yield and 95% enantiomeric excess of the (R)-enantiomer | ? |