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Literature summary for 3.1.3.101 extracted from

  • Asamizu, S.; Yang, J.; Almabruk, K.H.; Mahmud, T.
    Pseudoglycosyltransferase catalyzes nonglycosidic C-N coupling in validamycin a biosynthesis (2011), J. Am. Chem. Soc., 133, 12124-12135.
    View publication on PubMedView publication on EuropePMC

Cloned(Commentary)

Cloned (Comment) Organism
expression in Escherichia coli Streptomyces hygroscopicus subsp. limoneus

Natural Substrates/ Products (Substrates)

Natural Substrates Organism Comment (Nat. Sub.) Natural Products Comment (Nat. Pro.) Rev. Reac.
validoxylamine A 7'-phosphate + H2O Streptomyces hygroscopicus subsp. limoneus the enhzyme is involved in the biosynthesis of the antifungal agent validamycin A validoxylamine A + phosphate
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?

Organism

Organism UniProt Comment Textmining
Streptomyces hygroscopicus subsp. limoneus Q15JF8
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-

Purification (Commentary)

Purification (Comment) Organism
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Streptomyces hygroscopicus subsp. limoneus

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
trehalose 6-phosphate + H2O
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Streptomyces hygroscopicus subsp. limoneus trehalose + phosphate
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?
validoxylamine A 7'-phosphate + H2O
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Streptomyces hygroscopicus subsp. limoneus validoxylamine A + phosphate validoxylamine A i.e. (1S,2S,3R,6S)-4-(hydroxymethyl)-6-[[(1S,2S,3S,4R,5R)-2,3,4-trihydroxy-5-(hydroxymethyl)cyclohexyl]amino]cyclohex-4-ene-1,2,3-triol ?
validoxylamine A 7'-phosphate + H2O the enhzyme is involved in the biosynthesis of the antifungal agent validamycin A Streptomyces hygroscopicus subsp. limoneus validoxylamine A + phosphate
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?

Synonyms

Synonyms Comment Organism
vldH
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Streptomyces hygroscopicus subsp. limoneus

General Information

General Information Comment Organism
metabolism the enzyme is involved in the biosynthesis of the aminocyclitol antibiotic validamycin A Streptomyces hygroscopicus subsp. limoneus