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Literature summary for 3.1.1.42 extracted from
- Chlorogenate hydrolase-catalyzed synthesis of hydroxycinnamic acid ester derivatives by transesterification, substitution of bromine, and condensation reactions (2005), Appl. Microbiol. Biotechnol., 68, 198-202.
Organism
| Organism | UniProt | Comment | Textmining |
|---|---|---|---|
| Aspergillus japonicus | - |
- |
- |
Substrates and Products (Substrate)
| Substrates | Comment Substrates | Organism | Products | Comment (Products) | Rev. | Reac. |
|---|---|---|---|---|---|---|
| 1-phenylethyl alcohol + 5-chlorogenic acid | - |
Aspergillus japonicus | (S)-1-phenylethyl caffeate + quinate | transesterification reaction, about 50% molar conversion yield | ? |  |
| 2-phenylethyl alcohol + 5-chlorogenic acid | - |
Aspergillus japonicus | 2-phenylethyl caffeate + quinate | transesterification reaction, about 50% molar conversion yield | ? | |
| 2-phenylethyl bromide + 5-chlorogenic acid | - |
Aspergillus japonicus | 2-phenylethyl caffeate + 5-bromo-quinate | substitution reaction, about 2.3% molar conversion yield, no substrate: phenylethyl chloride, phenylethyl iodide | ? | |
| 3-(3,4-dihydroxyphenyl)-propionic acid + 1-phenylethyl alcohol | - |
Aspergillus japonicus | ? | - |
? | |
| additional information | no substrate: hydroxybenzoic acids, phenyl alkanoic acids with a C4 or C5 alkyl side chain, o-coumaric acid, 4-nitrocinnamic acid, and aromatic amino acids | Aspergillus japonicus | ? | - |
? | |
| p-coumaric acid + 2-phenylethyl bromide | - |
Aspergillus japonicus | 2-phenylethyl p-coumarate + bromide | about 90% molar conversion yield | ? | |
| phenylpropyl bromide + 5-chlorogenic acid | - |
Aspergillus japonicus | (S)-1-phenylpropyl caffeate + 5-bromo-quinate | about 2.3% molar conversion yield | r | |
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