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Literature summary for 1.8.5.3 extracted from

  • Abo, M.; Tachibana, M.; Okubo, A.; Yamazaki, S.
    Enantioselective deoxygenation of alkyl aryl sulfoxides by DMSO reductase from Rhodobacter sphaeroides f.s. denitrificans (1995), Bioorg. Med. Chem., 3, 109-112.
    View publication on PubMed
Search for more literature for 1.8.5.3

Organism

Organism UniProt Comment Textmining
Cereibacter sphaeroides
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Cereibacter sphaeroides f.s. denitrificans
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Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
(ethylsulfinyl)benzene + reduced benzyl viologen 90% of the rate with dimethysulfoxide Cereibacter sphaeroides (ethylsulfanyl)benzene + H2O + oxidized benzyl viologen
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(ethylsulfinyl)benzene + reduced benzyl viologen 90% of the rate with dimethysulfoxide Cereibacter sphaeroides f.s. denitrificans (ethylsulfanyl)benzene + H2O + oxidized benzyl viologen
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 ?
(methylsulfinyl)benzene + reduced benzyl viologen 150% of the rate with dimethysulfoxide Cereibacter sphaeroides (methylsulfanyl)benzene + H2O + oxidized benzyl viologen
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 ?
(methylsulfinyl)benzene + reduced benzyl viologen 150% of the rate with dimethysulfoxide Cereibacter sphaeroides f.s. denitrificans (methylsulfanyl)benzene + H2O + oxidized benzyl viologen
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 ?
(propan-2-ylsulfinyl)benzene + reduced benzyl viologen 35% of the rate with dimethysulfoxide Cereibacter sphaeroides (propan-2-ylsulfanyl)benzene + H2O + oxidized benzyl viologen
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 ?
(propan-2-ylsulfinyl)benzene + reduced benzyl viologen 35% of the rate with dimethysulfoxide Cereibacter sphaeroides f.s. denitrificans (propan-2-ylsulfanyl)benzene + H2O + oxidized benzyl viologen
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 ?
(propylsulfanyl)benzene + reduced benzyl viologen 35% of the rate with dimethysulfoxide Cereibacter sphaeroides (propylsulfinyl)benzene + H2O + oxidized benzyl viologen
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(propylsulfanyl)benzene + reduced benzyl viologen 35% of the rate with dimethysulfoxide Cereibacter sphaeroides f.s. denitrificans (propylsulfinyl)benzene + H2O + oxidized benzyl viologen
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 ?
1-bromo-4-(methylsulfinyl)benzene + reduced benzyl viologen 180% of the rate with dimethysulfoxide Cereibacter sphaeroides 1-bromo-4-(methylsulfanyl)benzene + H2O + oxidized benzyl viologen
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1-methyl-4-(methylsulfinyl)benzene + reduced benzyl viologen 150% of the rate with dimethysulfoxide Cereibacter sphaeroides 1-methyl-4-(methylsulfanyl)benzene + H2O + oxidized benzyl viologen
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dimethylsulfoxide + reduced benzyl viologen
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 Cereibacter sphaeroides dimethylsulfide + H2O + oxidized benzyl viologen
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additional information for all substrates studied, enzyme catalyzes deoxygenation of (S)-sulfoxides predominantly Cereibacter sphaeroides ?
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additional information for all substrates studied, enzyme catalyzes deoxygenation of (S)-sulfoxides predominantly Cereibacter sphaeroides f.s. denitrificans ?
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[(methylsulfinyl)methyl]benzene + reduced benzyl viologen 130% of the rate with dimethysulfoxide Cereibacter sphaeroides [(methylsulfanyl)methyl]benzene + H2O + oxidized benzyl viologen
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