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Literature summary for 1.14.14.155 extracted from

  • Beecher, J.; Grogan, G.; Roberts, S.; Willetts, A.
    Enantioselective oxidations by the diketocamphane monooxygenase isoenzymes from Pseudomonas putida (1996), Biotechnol. Lett., 18, 571-576.
No PubMed abstract available

Natural Substrates/ Products (Substrates)

Natural Substrates Organism Comment (Nat. Sub.) Natural Products Comment (Nat. Pro.) Rev. Reac.
(-)-bornane-2,5-dione + FMNH2 + O2 Pseudomonas putida inducible by growth on (+)-camphor ?
-
?
(-)-bornane-2,5-dione + FMNH2 + O2 Pseudomonas putida NCIMB 10007 inducible by growth on (+)-camphor ?
-
?

Organism

Organism UniProt Comment Textmining
Pseudomonas putida
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-
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Pseudomonas putida
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2 isozymes termed 2,5-diketocamphane-1,2-monooxygenase and 3,6-diketocamphane-1,6-monooxygenase
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Pseudomonas putida NCIMB 10007
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-
-

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
(-)-bornane-2,5-dione + FMNH2 + O2 6-dione i.e. 3,6-diketocamphane Pseudomonas putida 1,8,8-trimethyl-2-oxabicyclo[3.2.1]octane-3,6-dione + FMN + H2O
-
?
(-)-bornane-2,5-dione + FMNH2 + O2 6-dione i.e. 3,6-diketocamphane Pseudomonas putida NCIMB 10007 1,8,8-trimethyl-2-oxabicyclo[3.2.1]octane-3,6-dione + FMN + H2O
-
?
(-)-bornane-2,5-dione + FMNH2 + O2 inducible by growth on (+)-camphor Pseudomonas putida ?
-
?
(-)-bornane-2,5-dione + FMNH2 + O2 inducible by growth on (+)-camphor Pseudomonas putida NCIMB 10007 ?
-
?

Synonyms

Synonyms Comment Organism
3,6-diketocamphane 1,6-monooxygenase isoform, which is probably a different enzyme Pseudomonas putida
More lower regio- and enatioselectivity than isoform 2,5-diketocamphane-1,2-monooxygenase Pseudomonas putida