Any feedback?
Please rate this page
(literature.php)
(0/150)

BRENDA support

Literature summary for 1.14.13.84 extracted from

  • Rodriguez, C.; De Gonzalo, G.; Fraaije, M.W.; Gotor, V.
    Enzymatic kinetic resolution of racemic ketones catalyzed by Baeyer-Villiger monooxygenases (2007), Tetrahedron Asymmetry, 18, 1338-1344.
No PubMed abstract available
Search for more literature for 1.14.13.84

KM Value [mM]

KM Value [mM] KM Value Maximum [mM] Substrate Comment Organism Structure
additional information
-
 additional information kinetic resolution of the racemic carbonyl compounds, overview Pseudomonas fluorescens

Natural Substrates/ Products (Substrates)

Natural Substrates Organism Comment (Nat. Sub.) Natural Products Comment (Nat. Pro.) Rev. Reac.
4-hydroxyacetophenone + NADPH + H+ + O2 Pseudomonas fluorescens
-
 4-hydroxyphenyl acetate + NADP+ + H2O
-
 ?

Organism

Organism UniProt Comment Textmining
Pseudomonas fluorescens
-
-
-

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
(R)-2-phenylpentan-3-one + NADPH + H+ + O2
-
 Pseudomonas fluorescens ?
-
 ?
(R)-3-phenylbutan-2-one + NADPH + H+ + O2
-
 Pseudomonas fluorescens ?
-
 ?
(R)-3-phenylpentan-2-one + NADPH + H+ + O2
-
 Pseudomonas fluorescens ?
-
 ?
(R)-4-phenylhexan-2-one + NADPH + H+ + O2
-
 Pseudomonas fluorescens ?
-
 ?
2-phenylpentan-3-one + NADPH + H+ + O2
-
 Pseudomonas fluorescens ?
-
 ?
2-phenylpropionaldehyde + NADPH + H+ + O2
-
 Pseudomonas fluorescens ?
-
 ?
4-hydroxyacetophenone + NADPH + H+ + O2
-
 Pseudomonas fluorescens 4-hydroxyphenyl acetate + NADP+ + H2O
-
 ?
4-hydroxyacetophenone + NADPH + H+ + O2 enantiospecific reaction, overview Pseudomonas fluorescens 4-hydroxyphenyl acetate + NADP+ + H2O
-
 ?
additional information a Bayer-Villinger monooxygenase, substrate specificity with several racemic cyclic and linear ketones, as well as 2-phenylpropionaldehyde, high enantioselectivites can be obtained in the kinetic resolution processes depending on the substrate structure and the reaction conditions, overview Pseudomonas fluorescens ?
-
 ?

Synonyms

Synonyms Comment Organism
HAPMO
-
 Pseudomonas fluorescens

pH Optimum

pH Optimum Minimum pH Optimum Maximum Comment Organism
8 9 assay at Pseudomonas fluorescens

pH Range

pH Minimum pH Maximum Comment Organism
6 10 effects of pH on enantioselectivity, overview Pseudomonas fluorescens

Cofactor

Cofactor Comment Organism Structure
NADPH
-
 Pseudomonas fluorescens