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Literature summary for 1.14.12.17 extracted from

  • Yokoyama, A.; Han, J.E.; Cho, J.; Kubo, M.; Ogura, T.; Siegler, M.A.; Karlin, K.D.; Nam, W.
    Chromium(IV)-peroxo complex formation and its nitric oxide dioxygenase reactivity (2012), J. Am. Chem. Soc., 134, 15269-15272.
    View publication on PubMedView publication on EuropePMC
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Organism

Organism UniProt Comment Textmining
synthetic construct
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Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
additional information reaction of the [CrII(12-N-tetramethylated cyclam ligand)]2+ complex with O2 and NO. The starting Cr(II) complex [CrII(12-N-tetramethylated cyclam)(Cl)]+ reacts with O2 or NO to produce a Cr(IV)-peroxo complex , [CrIV(12-N-tetramethylated cyclam)(O2)(Cl)]+ or a Cr(II)-nitrosyl complex which reacts with NO to give a Cr(III)-nitrato complex, which is most likely formed through a Cr(III)-peroxynitrite intermediate and involving atypical metal ion reduction chemistry synthetic construct ?
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