Inhibitors | Comment | Organism | Structure |
---|---|---|---|
Acetylphosphate | - |
Streptomyces viridochromogenes |
Organism | UniProt | Comment | Textmining |
---|---|---|---|
Streptomyces viridochromogenes | Q5IW40 | - |
- |
Substrates | Comment Substrates | Organism | Products | Comment (Products) | Rev. | Reac. |
---|---|---|---|---|---|---|
(2R)-hydroxypropylphosphonate + O2 | - |
Streptomyces viridochromogenes | 2-oxopropylphosphonate + hydroxymethylphosphonate + acetate | substrate partitions between conversion to 2-oxopropylphosphonate and hydroxymethylphosphonate | ? | |
1-hydroxy-2,2,2-trifluoroethylphosphonate + O2 | - |
Streptomyces viridochromogenes | trifluoroacetylphosphonate | - |
? | |
1-hydroxyethylphosphonate + O2 | - |
Streptomyces viridochromogenes | acetylphosphate | - |
? | |
2-hydroxyethylphosphonate + O2 | - |
Streptomyces viridochromogenes | hydroxymethylphosphonate + formate | - |
? | |
hydroxymethylphosphonate + O2 | - |
Streptomyces viridochromogenes | phosphate + formate | - |
? | |
additional information | results provide strong support for a mechanism that proceeds by hydroperoxylation followed by a Criegee rearrangement with a phosphorus-based migrating group and requires that the O-O bond of molecular oxygen is not cleaved prior to substrate activation. No substrate: O-formyl-hydroxymethylphosphonate, (2S)-hydroxypropylphosphonate | Streptomyces viridochromogenes | ? | - |
? |
Synonyms | Comment | Organism |
---|---|---|
PhdP | - |
Streptomyces viridochromogenes |