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Literature summary for 1.11.1.9 extracted from

  • Yin, Y.; Jiao, S.; Wang, Y.; Zhang, R.; Shi, Z.; Hu, X.
    Construction of a artificial glutathione peroxidase with temperature-dependent activity based on a supramolecular graft copolymer (2015), ChemBioChem, 16, 670-676 .
    View publication on PubMed

Application

Application Comment Organism
synthesis preparation of a supramolecular artificial glutathione peroxidase based on a supramolecular graft copolymer and the catalytic center ADA-Te-OH. The artificial glutathione peroxidase was constructed by supramolecular host-guest self-assembly and displays noticeable temperature-dependent catalytic activity and typical saturation kinetics behavior. The change in the self-assembled structure during the temperature-dependent process plays a significant role in the temperature-dependent catalytic behavior synthetic construct

Organism

Organism UniProt Comment Textmining
synthetic construct
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Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
cumene hydroperoxide + 2 2-nitro-5-sulfanylbenzoic acid
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synthetic construct 2-phenylpropan-2-ol + 3,3'-disulfanediylbis(6-nitrobenzoic acid) + H2O
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?
cumene hydroperoxide + 2 4-nitrobenzenethiol
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synthetic construct 2-phenylpropan-2-ol + 1,1'-disulfanediylbis(4-nitrobenzene) + H2O
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?
cumene hydroperoxide + 2 GSH
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synthetic construct 2-phenylpropan-2-ol + GSSG + H2O
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?