Literature summary for 1.11.1.10 extracted from

Bougioukou, D.J.; Smonou, I.
Chloroperoxidase-catalyzed oxidation of conjugated dienoic esters (2002), Tetrahedron Lett., 43, 339-342.

No PubMed abstract available

Search for more literature for 1.11.1.10

Organism

Organism	UniProt	Comment	Textmining
Leptoxyphium fumago	-	-	-

Substrates and Products (Substrate)

Substrates	Comment Substrates	Organism	Products	Comment (Products)	Rev.	Reac.
(3E,5E)-hepta-3,5-dien-2-one + tert-butyl hydroperoxide	-	Leptoxyphium fumago	(2E,4E)-6-oxohepta-2,4-dienal + (3E)-4-(3-methyloxiran-2-yl)but-3-en-2-one + (2E)-4-oxopent-2-enal	83% (2E,4E)-6-oxohepta-2,4-dienal, 4% (3E)-4-(3-methyloxiran-2-yl)but-3-en-2-one, and 13% (2E)-4-oxopent-2-enal	?
(3Z,5E)-hepta-3,5-dien-2-one + tert-butyl hydroperoxide	-	Leptoxyphium fumago	(2E,4Z)-6-oxohepta-2,4-dienal + (2E)-4-oxopent-2-enal + (2E,4E)-6-oxohepta-2,4-dienal	78% (2E,4Z)-6-oxohepta-2,4-dienal, 15% (2E)-4-oxopent-2-enal and 7% (2E,4E)-6-oxohepta-2,4-dienal	?
(3Z,5Z)-hepta-3,5-dien-2-one + tert-butyl hydroperoxide	-	Leptoxyphium fumago	(2E,4Z)-6-oxohepta-2,4-dienal + (2E)-4-oxopent-2-enal + (3Z)-4-[(2S,3S)-3-methyloxiran-2-yl]but-3-en-2-one	27% (2E,4Z)-6-oxohepta-2,4-dienal, 38% (3E)-4-(3-methyloxiran-2-yl)but-3-en-2-one and 35% (3Z)-4-[(2S,3S)-3-methyloxiran-2-yl]but-3-en-2-one	?
additional information	in halide-independent oxidation reactions, CPO uses H2O2 or other organic peroxides as the source of oxygen without requiring cofactors	Leptoxyphium fumago	?	-	?

Synonyms

Synonyms	Comment	Organism
chloroperoxidase	-	Leptoxyphium fumago
CPO	-	Leptoxyphium fumago

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Release 2023.1 (January 2023)