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Literature summary for 1.1.99.B9 extracted from

  • Xue, Y.; Zhang, Y.; Wang, W.; Wang, Y.; Liu, Z.; Zou, S.; Zheng, Y.; Shen, Y.
    Highly enantioselective oxidation of alpha-hydroxyacids bearing a substituent with an aryl group: Co-production of optically active alpha-hydroxyacids and alpha-ketoacids (2013), Biores. Technol., 132, 391-394.
    View publication on PubMed
Search for more literature for 1.1.99.B9

KM Value [mM]

KM Value [mM] KM Value Maximum [mM] Substrate Comment Organism Structure
3.6
-
 (2S)-(4-bromophenyl)(hydroxy)acetic acid pH 8.0, 30°C Sinorhizobium sp.
3.7
-
 (2S)-(4-chlorophenyl)(hydroxy)acetic acid pH 8.0, 30°C Sinorhizobium sp.
4.9
-
 (2S)-(3-chlorophenyl)(hydroxy)acetic acid pH 8.0, 30°C Sinorhizobium sp.
8.6
-
 (2S)-hydroxy(3,5-difluorophenyl)acetic acid pH 8.0, 30°C Sinorhizobium sp.
11.5
-
 (2S)-(2-fluorophenyl)(hydroxy)acetic acid pH 8.0, 30°C Sinorhizobium sp.
15.2
-
 (2S)-hydroxy(2,4-difluorophenyl)acetic acid pH 8.0, 30°C Sinorhizobium sp.
64.9
-
 (2S)-hydroxy(phenyl)acetic acid pH 8.0, 30°C Sinorhizobium sp.
65.6
-
 (2S)-hydroxy(4-methylphenyl)acetic acid pH 8.0, 30°C Sinorhizobium sp.
66.5
-
 (2S)-(4-fluorophenyl)(hydroxy)acetic acid pH 8.0, 30°C Sinorhizobium sp.
68.5
-
 (2S)-hydroxy-3-phenylpropanoic acid pH 8.0, 30°C Sinorhizobium sp.
73.5
-
 (2S)-hydroxy(4-hydroxyphenyl)acetic acid pH 8.0, 30°C Sinorhizobium sp.
81.2
-
 (2S)-(2-chlorophenyl)(hydroxy)acetic acid pH 8.0, 30°C Sinorhizobium sp.

Organism

Organism UniProt Comment Textmining
Sinorhizobium sp.
-
-
-
Sinorhizobium sp. ZJB1101
-
-
-

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
(2S)-(2-chlorophenyl)(hydroxy)acetic acid + acceptor
-
 Sinorhizobium sp. (2-chlorophenyl)(oxo)acetic acid + reduced acceptor
-
 ?
(2S)-(2-chlorophenyl)(hydroxy)acetic acid + acceptor
-
 Sinorhizobium sp. ZJB1101 (2-chlorophenyl)(oxo)acetic acid + reduced acceptor
-
 ?
(2S)-(2-fluorophenyl)(hydroxy)acetic acid + acceptor
-
 Sinorhizobium sp. (2-fluorophenyl)(oxo)acetic acid + reduced acceptor
-
 ?
(2S)-(3-chlorophenyl)(hydroxy)acetic acid + acceptor
-
 Sinorhizobium sp. (3-chlorophenyl)(oxo)acetic acid + reduced acceptor
-
 ?
(2S)-(3-chlorophenyl)(hydroxy)acetic acid + acceptor
-
 Sinorhizobium sp. ZJB1101 (3-chlorophenyl)(oxo)acetic acid + reduced acceptor
-
 ?
(2S)-(4-bromophenyl)(hydroxy)acetic acid + acceptor
-
 Sinorhizobium sp. (4-bromophenyl)(oxo)acetic acid + reduced acceptor
-
 ?
(2S)-(4-chlorophenyl)(hydroxy)acetic acid + acceptor
-
 Sinorhizobium sp. (4-chlorophenyl)(oxo)acetic acid + reduced acceptor
-
 ?
(2S)-(4-fluorophenyl)(hydroxy)acetic acid + acceptor
-
 Sinorhizobium sp. (4-fluorophenyl)(oxo)acetic acid + reduced acceptor
-
 ?
(2S)-hydroxy(2,4-difluorophenyl)acetic acid + acceptor
-
 Sinorhizobium sp. (2,4-difluorophenyl)(oxo)acetic acid + reduced acceptor
-
 ?
(2S)-hydroxy(3,5-difluorophenyl)acetic acid + acceptor
-
 Sinorhizobium sp. (3,5-difluorophenyl)(oxo)acetic acid + reduced acceptor
-
 ?
(2S)-hydroxy(4-hydroxyphenyl)acetic acid + acceptor
-
 Sinorhizobium sp. (4-hydroxyphenyl)(oxo)acetic acid + reduced acceptor
-
 ?
(2S)-hydroxy(4-methylphenyl)acetic acid + acceptor
-
 Sinorhizobium sp. (4-methylphenyl)(oxo)acetic acid + reduced acceptor
-
 ?
(2S)-hydroxy(phenyl)acetic acid + acceptor
-
 Sinorhizobium sp. oxo(phenyl)acetic acid + reduced acceptor
-
 ?
(2S)-hydroxy(phenyl)acetic acid + acceptor
-
 Sinorhizobium sp. ZJB1101 oxo(phenyl)acetic acid + reduced acceptor
-
 ?
(2S)-hydroxy-3-phenylpropanoic acid + acceptor
-
 Sinorhizobium sp. 2-oxo-3-phenylpropanoic acid + reduced acceptor
-
 ?
(2S)-hydroxy-3-phenylpropanoic acid + acceptor
-
 Sinorhizobium sp. ZJB1101 2-oxo-3-phenylpropanoic acid + reduced acceptor
-
 ?
additional information enzyme is a stereoselective 2-hydroxyacid dehydrogenase (2-HADH) that can catalyze asymmetric oxidation of mandelic acid and 2-chloromandelic acid into corresponding 2-ketoacids and (R)-isomers with high activity and enantioselectivity, while no consecutive oxidation of 2-ketoacids is observed Sinorhizobium sp. ?
-
 ?
additional information enzyme is a stereoselective 2-hydroxyacid dehydrogenase (2-HADH) that can catalyze asymmetric oxidation of mandelic acid and 2-chloromandelic acid into corresponding 2-ketoacids and (R)-isomers with high activity and enantioselectivity, while no consecutive oxidation of 2-ketoacids is observed Sinorhizobium sp. ZJB1101 ?
-
 ?