Organism | UniProt | Comment | Textmining |
---|---|---|---|
Aerococcus viridans | Q44467 | - |
- |
Substrates | Comment Substrates | Organism | Products | Comment (Products) | Rev. | Reac. |
---|---|---|---|---|---|---|
(S)-2-hydroxy-2-phenylacetate + O2 | - |
Aerococcus viridans | phenylpyruvate + H2O2 | - |
? | |
2-hydroxy-2-(4-chlorophenyl)acetate + O2 | - |
Aerococcus viridans | (4-chlorophenyl)pyruvate + H2O2 | - |
? | |
2-hydroxy-2-(4-hydroxyphenyl)acetate + O2 | - |
Aerococcus viridans | (4-hydroxyphenyl)pyruvate + H2O2 | - |
? | |
2-hydroxy-2-(4-methoxyphenyl)acetate + O2 | - |
Aerococcus viridans | (4-methoxyphenyl)pyruvate + H2O2 | - |
? | |
2-hydroxy-2-(4-methylphenyl)acetate + O2 | - |
Aerococcus viridans | (4-methylphenyl)pyruvate + H2O2 | - |
? | |
2-hydroxy-2-(4-nitrophenyl)acetate + O2 | - |
Aerococcus viridans | (4-nitrophenyl)pyruvate + H2O2 | - |
? | |
L-alpha-hydroxy-beta-methylvalerate + O2 | - |
Aerococcus viridans | 3-methyl-2-oxopentanoate + H2O2 | - |
? | |
additional information | mechanism with little development of charge in the transition state, such as a transfer of hydride to the flavin N(5) position or a synchronous mechanism in which the alpha-C-H is formally abstracted as a H+ while the resulting charge is simultaneously neutralized by another event | Aerococcus viridans | ? | - |
? |
Turnover Number Minimum [1/s] | Turnover Number Maximum [1/s] | Substrate | Comment | Organism | Structure |
---|---|---|---|---|---|
6.6 | - |
(S)-2-Hydroxy-2-phenylacetate | mutant A95G, pH 7.0, 25°C | Aerococcus viridans | |
12 | - |
L-alpha-hydroxy-beta-methylvalerate | mutant A95G, pH 7.0, 25°C | Aerococcus viridans |
Cofactor | Comment | Organism | Structure |
---|---|---|---|
FMN | flavin reduction is a direct measure of alpha-C-H bond breakage | Aerococcus viridans |