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Literature summary for 1.1.1.404 extracted from

  • Rudolph, J.; Erbse, A.H.; Behlen, L.S.; Copley, S.D.
    A radical intermediate in the conversion of pentachlorophenol to tetrachlorohydroquinone by Sphingobium chlorophenolicum (2014), Biochemistry, 53, 6539-6549 .
    View publication on PubMedView publication on EuropePMC
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Natural Substrates/ Products (Substrates)

Natural Substrates Organism Comment (Nat. Sub.) Natural Products Comment (Nat. Pro.) Rev. Reac.
2,3,5,6-tetrachlorohydroquinone + NAD+ Sphingobium chlorophenolicum the enzyme participates in the degradation of pentachlorophenol 2,3,5,6-tetrachloro-1,4-benzoquinone + NADH + H+
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 ?

Organism

Organism UniProt Comment Textmining
Sphingobium chlorophenolicum
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-
-

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
2,3,5,6-tetrachlorohydroquinone + NAD+
-
 Sphingobium chlorophenolicum 2,3,5,6-tetrachloro-1,4-benzoquinone + NADH + H+
-
 ?
2,3,5,6-tetrachlorohydroquinone + NAD+ the enzyme participates in the degradation of pentachlorophenol Sphingobium chlorophenolicum 2,3,5,6-tetrachloro-1,4-benzoquinone + NADH + H+
-
 ?

Subunits

Subunits Comment Organism
homotrimer
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 Sphingobium chlorophenolicum

Synonyms

Synonyms Comment Organism
TCBQ reductase
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 Sphingobium chlorophenolicum

Cofactor

Cofactor Comment Organism Structure
FMN the enzyme is a homotrimer containing a flavin and an Fe2S2 cluster in each subunit Sphingobium chlorophenolicum
[2Fe-2S]-center the enzyme is a homotrimer containing a flavin and an Fe2S2 cluster in each subunit Sphingobium chlorophenolicum

General Information

General Information Comment Organism
metabolism the enzyme participates in the degradation of pentachlorophenol Sphingobium chlorophenolicum