Ligand dihydrocaffeoyl-CoA
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Basic Ligand Information
Molecular Structure

C30H44N7O19P3S
dihydrocaffeoyl-CoA
NDSCGRAEWDSLKF-FUEUKBNZSA-N
3,4-dihydroxyphenylpropanoyl-CoA, 3-(3,4-dihydroxyphenyl)propanoyl-CoA
Roles as Enzyme Ligand
In Vivo Substrate in Enzyme-catalyzed Reactions (1 result)
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3,4-dihydroxyphenylpropanoyl-CoA + (2E)-3-(3,4-dihydroxyphenyl)prop-2-enoate = 3,4-dihydroxyphenylpropanoate + (2E)-3-(3,4-dihydroxyphenyl)prop-2-enoyl-CoA
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In Vivo Product in Enzyme-catalyzed Reactions (1 result)
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(2E)-3-(3,4-dihydroxyphenyl)prop-2-enoyl-CoA + 2 NADH + 2 oxidized ferredoxin iron-sulfur cluster = 3-(3,4-dihydroxyphenyl)propanoyl-CoA + 2 NAD+ + 2 reduced ferredoxin iron-sulfur cluster
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Substrate in Enzyme-catalyzed Reactions (6 results)
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3,4-dihydroxyphenylpropanoyl-CoA + 3-(3,4-dihydroxyphenyl)lactate = CoA + 2-O-(3,4-dihydroxyphenylpropanoyl)-3-(3,4-dihydroxyphenyl)lactate
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3,4-dihydroxyphenylpropanoyl-CoA + 3-(4-hydroxyphenyl)lactate = CoA + 2-O-(3,4-dihydroxyphenylpropanoyl)-3-(4-hydroxyphenyl)lactate
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3,4-dihydroxyphenylpropanoyl-CoA + 3-phenyllactate = CoA + 2-O-(3,4-dihydroxyphenylpropanoyl)-3-phenyllactate
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3,4-dihydroxyphenylpropanoyl-CoA + (2E)-3-(3,4-dihydroxyphenyl)prop-2-enoate = 3,4-dihydroxyphenylpropanoate + (2E)-3-(3,4-dihydroxyphenyl)prop-2-enoyl-CoA
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3,4-dihydroxyphenylpropanoyl-CoA + 4-coumarate = 3,4-dihydroxyphenylpropanoate + 4-coumaroyl-CoA
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3,4-dihydroxyphenylpropanoyl-CoA + ferulate = 3,4-dihydroxyphenylpropanoate + feruloyl-CoA
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Product in Enzyme-catalyzed Reactions (1 result)
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(2E)-3-(3,4-dihydroxyphenyl)prop-2-enoyl-CoA + 2 NADH + 2 oxidized ferredoxin iron-sulfur cluster = 3-(3,4-dihydroxyphenyl)propanoyl-CoA + 2 NAD+ + 2 reduced ferredoxin iron-sulfur cluster
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Enzyme Kinetic Parameters
kcat Value (Turnover Number) (1 result)
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KM Value (1 result)
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References & Links
Literature References (2)
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Caffeate respiration in the acetogenic bacterium Acetobacterium woodii: a coenzyme A loop saves energy for caffeate activation
2013
Hess, V.; Gonzalez, J.M.; Parthasarathy, A.; Buckel, W.; Müller, V.
Appl. Environ. Microbiol.
79
1942-1947
Synthesis of rosmarinic acid analogues in Escherichia coli
2016
Zhuang, Y.; Jiang, J.; Bi, H.; Yin, H.; Liu, S.; Liu, T.
Biotechnol. Lett.
38
619-627
Links to other databases for dihydrocaffeoyl-CoA