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Information on EC 4.99.1.5 - aliphatic aldoxime dehydratase

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IUBMB Comments
The enzyme from Pseudomonas chlororaphis contains Ca2+ and protoheme IX, the iron of which must be in the form Fe(II) for activity. The enzyme exhibits a strong preference for aliphatic aldoximes, such as butyraldoxime and acetaldoxime, over aromatic aldoximes, such as pyridine-2-aldoxime, which is a poor substrate. No activity was found with the aromatic aldoximes benzaldoxime and pyridine-4-aldoxime.
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The enzyme appears in viruses and cellular organisms
Synonyms
aldoxime dehydratase, aliphatic aldoxime dehydratase, alkylaldoxime dehydratase, OXD, OxdA, OxdB, OxdK, OxdRE, OxdRG, more
REACTION
REACTION DIAGRAM
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ORGANISM
UNIPROT
LITERATURE
an aliphatic aldoxime = an aliphatic nitrile + H2O
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; The enzyme from Pseudomonas chlororaphis contains Ca2+ and protoheme IX, the iron of which must be in the form Fe2+ for activity. The enzyme exhibits a strong preference for aliphatic aldoximes, such as butyraldoxime and acetaldoxime, over aromatic aldoximes, such as pyridine-2-aldoxime, which is a poor substrate. No activity was found with the aromatic aldoximes benzaldoxime and pyridine-4-aldoxime
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