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(1R,2R,3R,4R,5S,6S)-hexachlorocyclohexane
1,3,4,5,6-pentachlorocyclohex-1-ene + HCl
(1R,2R,3S,4S,5S,6S)-1,2,3,4,5,6-hexachlorocyclohexane
1,3,4,5,6-pentachlorocyclohex-1-ene + HCl
1,3,4,5,6-pentachlorocyclohexene
1,3,4,6-tetrachloro-1,4-cyclohexadiene + HCl
alpha-hexachlorocyclohexane
beta-pentachlorocyclohexene + HCl
delta-hexachlorocyclohexane
1,3,4,6-tetrachloro-1,4-cyclohexadiene + 2 HCl
delta-pentachlorocyclohexene
1,3,4,6-tetrachloro-1,4-cyclohexadiene + HCl
gamma-hexachlorocyclohexane
1,3,4,6-tetrachloro-1,4-cyclohexadiene + 2 HCl
gamma-hexachlorocyclohexane
gamma-pentachlorocyclohexene + HCl
gamma-hexachlorocyclohexane
pentachlorocyclohexene + HCl
gamma-pentachlorocyclohexene
1,3,4,6-tetrachloro-1,4-cyclohexadiene + HCl
(1R,2R,3R,4R,5S,6S)-hexachlorocyclohexane
1,3,4,5,6-pentachlorocyclohex-1-ene + HCl
i.e. (+)-alpha-hexachlorocyclohexane. Isoform LinA1 shows enantioselectivity for the substrate and the product formed
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-
?
(1R,2R,3R,4R,5S,6S)-hexachlorocyclohexane
1,3,4,5,6-pentachlorocyclohex-1-ene + HCl
i.e. (+)-alpha-hexachlorocyclohexane. Isoform LinA1 shows enantioselectivity for the substrate and the product formed
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-
?
(1R,2R,3S,4S,5S,6S)-1,2,3,4,5,6-hexachlorocyclohexane
1,3,4,5,6-pentachlorocyclohex-1-ene + HCl
i.e. (-)-alpha-hexachlorocyclohexane. Isoform LinA2 shows enantioselectivity for the substrate and the product formed
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-
?
(1R,2R,3S,4S,5S,6S)-1,2,3,4,5,6-hexachlorocyclohexane
1,3,4,5,6-pentachlorocyclohex-1-ene + HCl
i.e. (-)-alpha-hexachlorocyclohexane. Isoform LinA2 shows enantioselectivity for the substrate and the product formed
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-
?
1,3,4,5,6-pentachlorocyclohexene
1,3,4,6-tetrachloro-1,4-cyclohexadiene + HCl
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?
1,3,4,5,6-pentachlorocyclohexene
1,3,4,6-tetrachloro-1,4-cyclohexadiene + HCl
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?
1,3,4,5,6-pentachlorocyclohexene
1,3,4,6-tetrachloro-1,4-cyclohexadiene + HCl
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?
alpha-hexachlorocyclohexane
beta-pentachlorocyclohexene + HCl
-
the product spontaneously reacts to 1,2,4-trichlorobenzene + HCl
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?
alpha-hexachlorocyclohexane
beta-pentachlorocyclohexene + HCl
-
the product spontaneously reacts to 1,2,4-trichlorobenzene + HCl
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?
alpha-hexachlorocyclohexane
beta-pentachlorocyclohexene + HCl
-
the product spontaneously reacts to 1,2,4-trichlorobenzene + HCl
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?
alpha-hexachlorocyclohexane
beta-pentachlorocyclohexene + HCl
-
the product spontaneously reacts to 1,2,4-trichlorobenzene + HCl
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?
alpha-hexachlorocyclohexane
beta-pentachlorocyclohexene + HCl
-
the product spontaneously reacts to 1,2,4-trichlorobenzene + HCl
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?
alpha-hexachlorocyclohexane
beta-pentachlorocyclohexene + HCl
-
the product spontaneously reacts to 1,2,4-trichlorobenzene + HCl
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?
alpha-hexachlorocyclohexane
beta-pentachlorocyclohexene + HCl
-
the product spontaneously reacts to 1,2,4-trichlorobenzene + HCl
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?
alpha-hexachlorocyclohexane
beta-pentachlorocyclohexene + HCl
-
the product spontaneously reacts to 1,2,4-trichlorobenzene + HCl
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?
alpha-hexachlorocyclohexane
beta-pentachlorocyclohexene + HCl
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the product spontaneously reacts to 1,2,4-trichlorobenzene + HCl
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?
delta-hexachlorocyclohexane
1,3,4,6-tetrachloro-1,4-cyclohexadiene + 2 HCl
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delta-pentachlorocyclohexene is formed as an intermediate
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?
delta-hexachlorocyclohexane
1,3,4,6-tetrachloro-1,4-cyclohexadiene + 2 HCl
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delta-pentachlorocyclohexene is formed as an intermediate
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?
delta-hexachlorocyclohexane
1,3,4,6-tetrachloro-1,4-cyclohexadiene + 2 HCl
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delta-pentachlorocyclohexene is formed as an intermediate
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?
delta-hexachlorocyclohexane
1,3,4,6-tetrachloro-1,4-cyclohexadiene + 2 HCl
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delta-pentachlorocyclohexene is formed as an intermediate
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?
delta-hexachlorocyclohexane
1,3,4,6-tetrachloro-1,4-cyclohexadiene + 2 HCl
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delta-pentachlorocyclohexene is formed as an intermediate
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?
delta-hexachlorocyclohexane
1,3,4,6-tetrachloro-1,4-cyclohexadiene + 2 HCl
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delta-pentachlorocyclohexene is formed as an intermediate
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?
delta-hexachlorocyclohexane
1,3,4,6-tetrachloro-1,4-cyclohexadiene + 2 HCl
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delta-pentachlorocyclohexene is formed as an intermediate
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?
delta-hexachlorocyclohexane
1,3,4,6-tetrachloro-1,4-cyclohexadiene + 2 HCl
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delta-pentachlorocyclohexene is formed as an intermediate
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?
delta-hexachlorocyclohexane
1,3,4,6-tetrachloro-1,4-cyclohexadiene + 2 HCl
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delta-pentachlorocyclohexene is formed as an intermediate
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?
delta-pentachlorocyclohexene
1,3,4,6-tetrachloro-1,4-cyclohexadiene + HCl
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?
delta-pentachlorocyclohexene
1,3,4,6-tetrachloro-1,4-cyclohexadiene + HCl
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?
delta-pentachlorocyclohexene
1,3,4,6-tetrachloro-1,4-cyclohexadiene + HCl
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?
delta-pentachlorocyclohexene
1,3,4,6-tetrachloro-1,4-cyclohexadiene + HCl
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?
delta-pentachlorocyclohexene
1,3,4,6-tetrachloro-1,4-cyclohexadiene + HCl
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?
delta-pentachlorocyclohexene
1,3,4,6-tetrachloro-1,4-cyclohexadiene + HCl
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?
delta-pentachlorocyclohexene
1,3,4,6-tetrachloro-1,4-cyclohexadiene + HCl
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?
delta-pentachlorocyclohexene
1,3,4,6-tetrachloro-1,4-cyclohexadiene + HCl
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?
delta-pentachlorocyclohexene
1,3,4,6-tetrachloro-1,4-cyclohexadiene + HCl
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?
gamma-hexachlorocyclohexane
1,3,4,6-tetrachloro-1,4-cyclohexadiene + 2 HCl
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?
gamma-hexachlorocyclohexane
1,3,4,6-tetrachloro-1,4-cyclohexadiene + 2 HCl
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?
gamma-hexachlorocyclohexane
1,3,4,6-tetrachloro-1,4-cyclohexadiene + 2 HCl
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gamma-pentachlorocyclohexene is formed as an intermediate
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?
gamma-hexachlorocyclohexane
1,3,4,6-tetrachloro-1,4-cyclohexadiene + 2 HCl
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gamma-pentachlorocyclohexene is formed as an intermediate
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?
gamma-hexachlorocyclohexane
1,3,4,6-tetrachloro-1,4-cyclohexadiene + 2 HCl
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gamma-pentachlorocyclohexene is formed as an intermediate
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?
gamma-hexachlorocyclohexane
1,3,4,6-tetrachloro-1,4-cyclohexadiene + 2 HCl
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gamma-pentachlorocyclohexene is formed as an intermediate
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?
gamma-hexachlorocyclohexane
1,3,4,6-tetrachloro-1,4-cyclohexadiene + 2 HCl
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gamma-pentachlorocyclohexene is formed as an intermediate
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?
gamma-hexachlorocyclohexane
1,3,4,6-tetrachloro-1,4-cyclohexadiene + 2 HCl
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gamma-pentachlorocyclohexene is formed as an intermediate
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?
gamma-hexachlorocyclohexane
1,3,4,6-tetrachloro-1,4-cyclohexadiene + 2 HCl
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gamma-pentachlorocyclohexene is formed as an intermediate
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?
gamma-hexachlorocyclohexane
1,3,4,6-tetrachloro-1,4-cyclohexadiene + 2 HCl
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gamma-pentachlorocyclohexene is formed as an intermediate
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?
gamma-hexachlorocyclohexane
1,3,4,6-tetrachloro-1,4-cyclohexadiene + 2 HCl
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gamma-pentachlorocyclohexene is formed as an intermediate
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?
gamma-hexachlorocyclohexane
gamma-pentachlorocyclohexene + HCl
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?
gamma-hexachlorocyclohexane
gamma-pentachlorocyclohexene + HCl
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?
gamma-hexachlorocyclohexane
gamma-pentachlorocyclohexene + HCl
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?
gamma-hexachlorocyclohexane
pentachlorocyclohexene + HCl
activity differs with isomers alpha, gamma, and delta, for LinA type 1 the activity is highest with the alpha isomer, no activity with the beta isomer
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?
gamma-hexachlorocyclohexane
pentachlorocyclohexene + HCl
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-
?
gamma-hexachlorocyclohexane
pentachlorocyclohexene + HCl
activity differs with isomers alpha, gamma, and delta, for LinA type 1 the activity is highest with the gamma-isomer, no activity with the beta isomer
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-
?
gamma-hexachlorocyclohexane
pentachlorocyclohexene + HCl
activity differs with isomers alpha, gamma, and delta, for LinA type 2 the activity is highest with the alpha-isomer, no activity with the beta isomer
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-
?
gamma-hexachlorocyclohexane
pentachlorocyclohexene + HCl
activity differs with isomers alpha, gamma, and delta, LinA-type1 exhibits enantioselectivity for the (-)-enantiomer of alpha-hexachlorocyclohexane
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-
?
gamma-hexachlorocyclohexane
pentachlorocyclohexene + HCl
activity differs with isomers alpha, gamma, and delta, LinA-type2 exhibits enantioselectivity for the (+)-enantiomer of alpha-hexachlorocyclohexane
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?
gamma-pentachlorocyclohexene
1,3,4,6-tetrachloro-1,4-cyclohexadiene + HCl
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?
gamma-pentachlorocyclohexene
1,3,4,6-tetrachloro-1,4-cyclohexadiene + HCl
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?
gamma-pentachlorocyclohexene
1,3,4,6-tetrachloro-1,4-cyclohexadiene + HCl
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?
gamma-pentachlorocyclohexene
1,3,4,6-tetrachloro-1,4-cyclohexadiene + HCl
-
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?
gamma-pentachlorocyclohexene
1,3,4,6-tetrachloro-1,4-cyclohexadiene + HCl
-
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?
gamma-pentachlorocyclohexene
1,3,4,6-tetrachloro-1,4-cyclohexadiene + HCl
-
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?
gamma-pentachlorocyclohexene
1,3,4,6-tetrachloro-1,4-cyclohexadiene + HCl
-
-
-
?
gamma-pentachlorocyclohexene
1,3,4,6-tetrachloro-1,4-cyclohexadiene + HCl
-
-
-
?
gamma-pentachlorocyclohexene
1,3,4,6-tetrachloro-1,4-cyclohexadiene + HCl
-
-
-
?
gamma-pentachlorocyclohexene
1,3,4,6-tetrachloro-1,4-cyclohexadiene + HCl
-
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?
gamma-pentachlorocyclohexene
1,3,4,6-tetrachloro-1,4-cyclohexadiene + HCl
-
-
-
?
gamma-pentachlorocyclohexene
1,3,4,6-tetrachloro-1,4-cyclohexadiene + HCl
-
-
-
?
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Zhang, H.; Wan, H.; Song, L.; Jiang, H.; Wang, H.; Qiao, C.
Development of an autofluorescent Pseudomonas nitroreducens with dehydrochlorinase activity for efficient mineralization of gamma-hexachlorocyclohexane (gamma-HCH)
J. Biotechnol.
146
114-119
2010
Sphingomonas paucimobilis (P51697)
brenda
Okai, M.; Kubota, K.; Fukuda, M.; Nagata, Y.; Nagata, K.; Tanokura, M.
Crystal structure of gamma-hexachlorocyclohexane dehydrochlorinase LinA from Sphingobium japonicum UT26
J. Mol. Biol.
403
260-269
2010
Sphingobium indicum, Sphingobium indicum UT26
brenda
Lal, R.; Pandey, G.; Sharma, P.; Kumari, K.; Malhotra, S.; Pandey, R.; Raina, V.; Kohler, H.P.; Holliger, C.; Jackson, C.; Oakeshott, J.G.
Biochemistry of microbial degradation of hexachlorocyclohexane and prospects for bioremediation
Microbiol. Mol. Biol. Rev.
74
58-80
2010
Sphingomonas paucimobilis (P51697), Sphingomonas paucimobilis (Q5EDH7), Sphingomonas sp. (Q599S6), Sphingomonas sp. (Q599S7), Sphingomonas sp. (Q599S8), Sphingomonas sp. (Q599S9), Sphingomonas sp. (Q599T0), Sphingomonas sp. (Q599T1), Sphingomonas sp. (Q599T2), Sphingomonas sp. (Q599T3), Sphingomonas sp. DS2 (Q599T2), Sphingomonas sp. DS2 (Q599T3), Sphingomonas sp. alpha4-2 (Q599S7), Sphingomonas sp. gamma12-7 (Q599T0), Sphingomonas sp. gamma1-7 (Q599T1), Sphingomonas sp. gamma16-1 (Q599S9), Sphingomonas sp. alpha1-2 (Q599S8), Sphingomonas sp. DS3-1 (Q599S6)
brenda
Macwan, A.S.; Javed, S.; Kumar, A.
Isolation of a novel thermostable dehydrochlorinase (LinA) from a soil metagenome
3 Biotech
1
193-198
2011
uncultured bacterium (B5ANU3), uncultured bacterium (B5ANV6), Sphingomonas paucimobilis (P51697)
brenda
Ito, M.; Ono, A.; Ohtsubo, Y.; Tsuda, M.; Nagata, Y.
Cloning of gamma-hexachlorocyclohexane dehydrochlorinase gene with its flanking regions from soil by activity-based screening techniques
Eur. J. Soil Biol.
52
16-19
2012
Sphingobium indicum (D4Z258), Sphingobium indicum (P59767), Sphingobium indicum (Q6VQZ2), Sphingomonas paucimobilis (Q5EDH7), Sphingobium indicum B90 (P59767), Sphingobium indicum B90A (Q6VQZ2), Sphingobium indicum UT26 (D4Z258)
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brenda
Macwan, A.S.; Kukshal, V.; Srivastava, N.; Javed, S.; Kumar, A.; Ramachandran, R.
Crystal structure of the hexachlorocyclohexane dehydrochlorinase (LinA-type2): mutational analysis, thermostability and enantioselectivity
PLoS ONE
7
e50373
2012
uncultured bacterium (B5ANU3), uncultured bacterium (B5ANV6)
brenda
Suar, M.; Hauser, A.; Poiger, T.; Buser, H.R.; Mller, M.D.; Dogra, C.; Raina, V.; Holliger, C.; van der Meer, J.R.; Lal, R.; Kohler, H.P.
Enantioselective transformation of a-hexachlorocyclohexaneby the dehydrochlorinases LinA1 and LinA2 from the soil bacterium Sphingomonas paucimobilis B90A
Appl. Environ. Microbiol.
71
8514-8518
2005
Sphingobium indicum (P59766), Sphingobium indicum (P59767), Sphingobium indicum B90A (P59766), Sphingobium indicum B90A (P59767)
brenda
Tang, X.; Zhang, R.; Zhang, Q.; Wang, W.
Dehydrochlorination mechanism of gamma-hexachlorocyclohexane degraded by dehydrochlorinase LinA from Sphingomonas paucimobilis UT26
RSC Adv.
6
4183-4192
2016
Sphingobium indicum (P51697), Sphingobium indicum DSM 16413 (P51697)
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brenda