Information on EC 4.2.3.86 - 7-epi-alpha-selinene synthase

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EC Tree
     4 Lyases
         4.2 Carbon-oxygen lyases
             4.2.3 Acting on phosphates
                4.2.3.86 7-epi-alpha-selinene synthase
IUBMB Comments
The recombinant enzyme from Vitis vinifera forms 49.5% (+)-valencene (cf. EC 4.2.3.73, valencene synthase) and 35.5% (-)-7-epi-alpha-selinene. Initial cyclization gives (+)-germacrene A in an enzyme bound form which is not released to the medium.
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The expected taxonomic range for this enzyme is: Vitis vinifera
Synonyms
selinene synthase, VvPNSeInt, VvVal, VvValCS, more
REACTION
REACTION DIAGRAM
COMMENTARY hide
ORGANISM
UNIPROT
LITERATURE
(2E,6E)-farnesyl diphosphate = 7-epi-alpha-selinene + diphosphate
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