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EC Tree
IUBMB Comments Isolated from the liverwort Heteroscyphus planus. cf EC 4.2.3.92 (+)-gamma-cadinene synthase.
The expected taxonomic range for this enzyme is: Bacteria, Eukaryota
Synonyms
TPS, TpsNY,
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TPS
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TPS
Cucumis melo variety Noy Yizre'el
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-
TpsNY
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TpsNY
Cucumis melo variety Noy Yizre'el
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-
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(2Z,6E)-farnesyl diphosphate = (-)-gamma-cadinene + diphosphate
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-
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-
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(2Z,6E)-farnesyl-diphosphate diphosphate-lyase [(-)-gamma-cadinene-forming]
Isolated from the liverwort Heteroscyphus planus. cf EC 4.2.3.92 (+)-gamma-cadinene synthase.
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(2Z, 6E)-farnesyl diphosphate
(-)-gamma-cadinene + diphosphate
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-
formation of gamma-cadinene involves a 1,3-hydride shift. (-)-gamma-Cadinene is directly formed from 2Z,6E-farnesyl diphosphate by intramolecular electrophilic attack of the primary carbocation on the C-10 position of farnesyl diphosphate. Second product: (+)-germacrene D
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?
farnesyl diphosphate
gamma-cadinene
farnesyl diphosphate
gamma-cadinene
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plus delta-cadinene plus minor amounts of alpha-copaene
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?
farnesyl diphosphate
gamma-cadinene
Cucumis melo variety Noy Yizre'el
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plus delta-cadinene plus minor amounts of alpha-copaene
-
?
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(2Z, 6E)-farnesyl diphosphate
(-)-gamma-cadinene + diphosphate
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-
formation of gamma-cadinene involves a 1,3-hydride shift. (-)-gamma-Cadinene is directly formed from 2Z,6E-farnesyl diphosphate by intramolecular electrophilic attack of the primary carbocation on the C-10 position of farnesyl diphosphate. Second product: (+)-germacrene D
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?
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UniProt
brenda
Cucumis melo variety Noy Yizre'el
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UniProt
brenda
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-
-
brenda
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rinds of mature fruits
brenda
Cucumis melo variety Noy Yizre'el
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rinds of mature fruits
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brenda
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GCAS_CHIPD
Chitinophaga pinensis (strain ATCC 43595 / DSM 2588 / LMG 13176 / NBRC 15968 / NCIMB 11800 / UQM 2034)
321
0
37087
Swiss-Prot
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GCSY1_CUCME
571
0
66633
Swiss-Prot
other Location (Reliability: 4 )
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expression in Escherichia coli
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Portnoy, V.; Benyamini, Y.; Bar, E.; Harel-Beja, R.; Gepstein, S.; Giovannoni, J.J.; Schaffer, A.A.; Burger, J.; Tadmor, Y.; Lewinsohn, E.; Katzir, N.
The molecular and biochemical basis for varietal variation in sesquiterpene content in melon (Cucumis melo L.) rinds
Plant Mol. Biol.
66
647-661
2008
Cucumis melo (B2KSJ5), Cucumis melo variety Noy Yizre'el (B2KSJ5)
brenda
Nabeta, K.; Fujita, M.; Komuro, K.; Katayama, K.; Takasawa, T.
In vitro biosynthesis of cadinanes by cell-free extracts of cultured cells of Heteroscyphus planus
J. Chem. Soc.
1
2065-2070
1997
Heteroscyphus planus
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brenda
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