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IUBMB CommentsIsolated from the plant Zea mays (maize). The product is named in the reference using a different numbering scheme for eudesmane.
The expected taxonomic range for this enzyme is: Zea mays
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maize eudesmanediol synthase
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ZmEDS
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(2E,6E)-farnesyl diphosphate + 2 H2O = 7-epi-ent-eudesmane-5,11-diol + diphosphate
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(2E,6E)-farnesyl-diphosphate diphosphate-lyase (cyclizing, 7-epi-ent-eudesmane-5,11-diol-forming)
Isolated from the plant Zea mays (maize). The product is named in the reference using a different numbering scheme for eudesmane.
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(2E,6E)-farnesyl diphosphate + 2 H2O
7-epi-ent-eudesmane-5,11-diol + diphosphate
(2E,6E)-farnesyl diphosphate + 2 H2O
7-epi-ent-eudesmane-5,11-diol + diphosphate
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(2E,6E)-farnesyl diphosphate + 2 H2O
7-epi-ent-eudesmane-5,11-diol + diphosphate
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7-epi-ent-eudesmane-5,11-diol i.e. (4S,4aS,6R,8aS)-6-(2-hydroxypropan-2-yl)-4,8a-dimethyldecahydronaphthalen-4a-ol
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(2E,6E)-farnesyl diphosphate + 2 H2O
7-epi-ent-eudesmane-5,11-diol + diphosphate
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brenda
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ZmEDS is specifically expressed in roots
brenda
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EDSB_MAIZE
557
0
63294
Swiss-Prot
other Location (Reliability: 4)
EDSM_MAIZE
557
0
63237
Swiss-Prot
other Location (Reliability: 4)
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F303A
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mutant enzyme shows predominant production of hedycarol
Y529F
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while the ZmEDS:Y529F mutant produces an increased amount of hedycaryol the other products, including the sesquiterpenoid diols, are still present
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expressed in Escherichia coli
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expressed in leaves of Nicotiana benthamiana
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infection with the fungal pathogen Fusarium verticillioides significantly induces accumulation of ZmEDS transcripts in roots
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Liang, J.; Liu, J.; Brown, R.; Jia, M.; Zhou, K.; Peters, R.; Wang, Q.
Direct production of dihydroxylated sesquiterpenoids by a maize terpene synthase
Plant J.
94
847-856
2018
Zea mays
brenda
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