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IUBMB Comments Isolated from the plants Pinus banksiana (jack pine) and Pinus contorta (lodgepole pine).
Synonyms
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monofunctional pimaradiene synthase 1
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(+)-copalyl diphosphate = pimara-8(14),15-diene + diphosphate
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(+)-copalyl diphosphate-lyase (pimara-8(14),15-diene-forming)
Isolated from the plants Pinus banksiana (jack pine) and Pinus contorta (lodgepole pine).
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(+)-copalyl diphosphate
aphidicol-15-ene + phosphate
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Substrates: -
?
(+)-copalyl diphosphate
pimara-7,15-diene + diphosphate
-
Substrates: -
?
(+)-copalyl diphosphate
pimara-8(14),15-diene + diphosphate
(+)-copalyl diphosphate
pimara-8(14),15-diene + diphosphate
Substrates: -
?
(+)-copalyl diphosphate
pimara-8(14),15-diene + diphosphate
Substrates: -
?
(+)-copalyl diphosphate
pimara-8(14),15-diene + diphosphate
Substrates: the enzyme is involved in diterpene biosynthesis
?
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(+)-copalyl diphosphate
pimara-8(14),15-diene + diphosphate
(+)-copalyl diphosphate
pimara-8(14),15-diene + diphosphate
Substrates: -
?
(+)-copalyl diphosphate
pimara-8(14),15-diene + diphosphate
Substrates: the enzyme is involved in diterpene biosynthesis
?
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brenda
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UniProt
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UniProt
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Highest Expressing Human Cell Lines
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Cell Line Links
Gene Links
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metabolism
the enzyme is involved in diterpene biosynthesis
metabolism
the enzyme is involved in diterpene biosynthesis
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MPIM1_PINBN
868
0
100159
Swiss-Prot
other Location (Reliability: 5 )
MPIM1_PINCO
868
0
100104
Swiss-Prot
other Location (Reliability: 5 )
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T696I
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mutation leads to a dramatic increase in reaction complexity. Product outcome is shifted from the tricyclic pimara-7,15-diene to a rearranged tetracycle, aphidicol-15-ene. Products are about 20% pimara-7,15-diene plus 80% aphidicol-15-ene
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Hall, D.; Zerbe, P.; Jancsik, S.; Quesada, A.; Dullat, H.; Madilao, L.; Yuen, M.; Bohlmann, J.
Evolution of conifer diterpene synthases: diterpene resin acid biosynthesis in lodgepole pine and jack pine involves monofunctional and bifunctional diterpene synthases
Plant Physiol.
161
600-616
2013
Pinus banksiana (M4HY08), Pinus contorta (M4HYC8)
brenda
Morrone, D.; Xu, M.; Fulton, D.B.; Determan, M.K.; Peters, R.J.
Increasing complexity of a diterpene synthase reaction with a single residue switch
J. Am. Chem. Soc.
130
5400-5401
2008
Oryza sativa
brenda
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