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Information on EC 3.1.1.108 - iron(III)-enterobactin esterase

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EC Tree
     3 Hydrolases
         3.1 Acting on ester bonds
             3.1.1 Carboxylic-ester hydrolases
                3.1.1.108 iron(III)-enterobactin esterase
IUBMB Comments
The enzyme, isolated from the bacterium Escherichia coli, allows the bacterium to grow in limited iron conditions. It can also act on enterobactin (with no complexed iron) and the aluminium(III) analogue of iron(III)-enterobactin. The trimer formed is further hydrolysed to form the dimer and the monomer.
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The enzyme appears in viruses and cellular organisms
Reaction Schemes
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iron(III)-enterobactin
+
3
=
iron(III)-N-(2,3-dihydroxybenzoyl)-L-serine complex
+
2
Synonyms
enterochelin esterase, enterochelin hydrolase, ferric enterobactin esterase, Fes, pfeE, more
REACTION
REACTION DIAGRAM
COMMENTARY hide
ORGANISM
UNIPROT
LITERATURE
iron(III)-enterobactin + 3 H2O = iron(III)-N-(2,3-dihydroxybenzoyl)-L-serine complex + 2 N-(2,3-dihydroxybenzoyl)-L-serine
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overall reaction
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iron(III)-enterobactin + H2O = iron(III)-N-(2,3-dihydroxybenzoyl)-L-serine trimer complex
show the reaction diagram
(1a)
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-
-
iron(III)-N-(2,3-dihydroxybenzoyl)-L-serine dimer complex + H2O = iron(III)-N-(2,3-dihydroxybenzoyl)-L-serine complex + N-(2,3-dihydroxybenzoyl)-L-serine
show the reaction diagram
(1c)
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-
-
iron(III)-N-(2,3-dihydroxybenzoyl)-L-serine trimer + H2O = iron(III)-N-(2,3-dihydroxybenzoyl)-L-serine dimer complex + N-(2,3-dihydroxybenzoyl)-L-serine
show the reaction diagram
(1b)
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-
-
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