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Information on EC 2.5.1.137 - 2-acyl-4-prenylphloroglucinol 6-prenyltransferase

for references in articles please use BRENDA:EC2.5.1.137
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IUBMB Comments
The enzyme, characterized from hop (Humulus lupulus), catalyses two successive prenylations of a 2-acyl-4-prenylphloroglucinol during the synthesis of bitter acids. Forms a complex with EC 2.5.1.136, 2-acylphloroglucinol 4-prenyltransferase, which catalyses the initial prenylation of the substrates. Requires Mg2+.
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The expected taxonomic range for this enzyme is: Humulus lupulus
Synonyms
aromatic prenyltransferase, PT2, more
REACTION
REACTION DIAGRAM
COMMENTARY hide
ORGANISM
UNIPROT
LITERATURE
dimethylallyl diphosphate + a 2-acyl-4,6-bisprenylphloroglucinol = diphosphate + a 2-acyl-4,6,6-trisprenylcyclohexa-2,4-dien-1-one
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(2)
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dimethylallyl diphosphate + a 2-acyl-4-prenylphloroglucinol = diphosphate + a 2-acyl-4,6-bisprenylphloroglucinol
show the reaction diagram
(1)
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