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5-O-beta-D-mycaminosyltylonolide + dTDP-6-deoxy-alpha-D-allose
dTDP + demethyllactenocin
5-O-beta-D-mycaminosyltylonolide + dTDP-6-deoxy-alpha-D-allose
dTDP + demethyllactenocin
Substrates: -
Products: demethyllactenocin i.e. [(2R,3R,4E,6E,9R,11R,12S,13S,14R)-12-[[3,6-dideoxy-3-(dimethylamino)-D-glucopyranosyl]oxy]-2-ethyl-14-hydroxy-5,9,13-trimethyl-8,16-dioxo-11-(2-oxoethyl)oxacyclohexadeca-4,6-dien-3-yl]methyl 6-deoxy-beta-D-allopyranoside
?
5-O-beta-D-mycaminosyltylonolide + dTDP-6-deoxy-alpha-D-allose
dTDP + demethyllactenocin
Substrates: the enzyme participates in the biosynthetic pathway of the macrolide antibiotic tylosin
Products: demethyllactenocin i.e. [(2R,3R,4E,6E,9R,11R,12S,13S,14R)-12-[[3,6-dideoxy-3-(dimethylamino)-D-glucopyranosyl]oxy]-2-ethyl-14-hydroxy-5,9,13-trimethyl-8,16-dioxo-11-(2-oxoethyl)oxacyclohexadeca-4,6-dien-3-yl]methyl 6-deoxy-beta-D-allopyranoside
?
5-O-beta-D-mycaminosyltylonolide + dTDP-6-deoxy-alpha-D-allose
dTDP + demethyllactenocin
Substrates: -
Products: demethyllactenocin i.e. [(2R,3R,4E,6E,9R,11R,12S,13S,14R)-12-[[3,6-dideoxy-3-(dimethylamino)-D-glucopyranosyl]oxy]-2-ethyl-14-hydroxy-5,9,13-trimethyl-8,16-dioxo-11-(2-oxoethyl)oxacyclohexadeca-4,6-dien-3-yl]methyl 6-deoxy-beta-D-allopyranoside
?
5-O-beta-D-mycaminosyltylonolide + dTDP-6-deoxy-alpha-D-allose
dTDP + demethyllactenocin
Substrates: the enzyme participates in the biosynthetic pathway of the macrolide antibiotic tylosin
Products: demethyllactenocin i.e. [(2R,3R,4E,6E,9R,11R,12S,13S,14R)-12-[[3,6-dideoxy-3-(dimethylamino)-D-glucopyranosyl]oxy]-2-ethyl-14-hydroxy-5,9,13-trimethyl-8,16-dioxo-11-(2-oxoethyl)oxacyclohexadeca-4,6-dien-3-yl]methyl 6-deoxy-beta-D-allopyranoside
?
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5-O-beta-D-mycaminosyltylonolide + dTDP-6-deoxy-alpha-D-allose
dTDP + demethyllactenocin
5-O-beta-D-mycaminosyltylonolide + dTDP-6-deoxy-alpha-D-allose
dTDP + demethyllactenocin
Substrates: the enzyme participates in the biosynthetic pathway of the macrolide antibiotic tylosin
Products: demethyllactenocin i.e. [(2R,3R,4E,6E,9R,11R,12S,13S,14R)-12-[[3,6-dideoxy-3-(dimethylamino)-D-glucopyranosyl]oxy]-2-ethyl-14-hydroxy-5,9,13-trimethyl-8,16-dioxo-11-(2-oxoethyl)oxacyclohexadeca-4,6-dien-3-yl]methyl 6-deoxy-beta-D-allopyranoside
?
5-O-beta-D-mycaminosyltylonolide + dTDP-6-deoxy-alpha-D-allose
dTDP + demethyllactenocin
Substrates: the enzyme participates in the biosynthetic pathway of the macrolide antibiotic tylosin
Products: demethyllactenocin i.e. [(2R,3R,4E,6E,9R,11R,12S,13S,14R)-12-[[3,6-dideoxy-3-(dimethylamino)-D-glucopyranosyl]oxy]-2-ethyl-14-hydroxy-5,9,13-trimethyl-8,16-dioxo-11-(2-oxoethyl)oxacyclohexadeca-4,6-dien-3-yl]methyl 6-deoxy-beta-D-allopyranoside
?
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