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EC Tree
IUBMB Comments Also acts on several diphenols and phenylenediamines, but has low affinity for these substrates. Involved in the biosynthesis of mould metabolites related to the antibiotic griseofulvin.
The enzyme appears in viruses and cellular organisms
Synonyms
EC 1.10.3.8, Oxidase, sulochrin, sulochrin oxidase ((-)-bisdechlorogeodin-forming),
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sulochrin oxidase ((-)-bisdechlorogeodin-forming)
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2 sulochrin + O2 = 2 (-)-bisdechlorogeodin + 2 H2O
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sulochrin:oxygen oxidoreductase (cyclizing, (-)-specific)
Also acts on several diphenols and phenylenediamines, but has low affinity for these substrates. Involved in the biosynthesis of mould metabolites related to the antibiotic griseofulvin.
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hydroquinone + O2
?
Oospora sulphurea-ochracea
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N,N,N',N'-tetramethyl-p-phenylenediamine + O2
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Oospora sulphurea-ochracea
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?
sulochrin + O2
(-)-bisdechlorogeodin + H2O
Oospora sulphurea-ochracea
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?
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copper
Oospora sulphurea-ochracea
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6 copper atoms per molecule
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Sodium diethyldithiocarbamate
Oospora sulphurea-ochracea
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0.1 mM, 66% inhibition, 1 mM, complete inhibition
additional information
Oospora sulphurea-ochracea
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not inhibited by 2 mM, neocuproin, 5 mM potassium cyanide or 10 mM EDTA
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53
hydroquinone
Oospora sulphurea-ochracea
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1.5
N,N,N',N'-tetramethyl-p-phenylenediamine
Oospora sulphurea-ochracea
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0.0085
sulochrin
Oospora sulphurea-ochracea
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-
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1.2
Oospora sulphurea-ochracea
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-
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5.8
Oospora sulphurea-ochracea
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-
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3.5 - 7
Oospora sulphurea-ochracea
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-
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25
Oospora sulphurea-ochracea
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assay at
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Oospora sulphurea-ochracea
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brenda
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Oospora sulphurea-ochracea
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brenda
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Oospora sulphurea-ochracea
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no extracellular activity
brenda
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128000
Oospora sulphurea-ochracea
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gel filtration
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glycoprotein
Oospora sulphurea-ochracea
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-20°C, pH 5.8, citrate-phosphate buffer, several months, no loss in activity
Oospora sulphurea-ochracea
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Oospora sulphurea-ochracea
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Nordlöv, H.; Gatenbeck, S.
Enzymatic synthesis of (+)- and (-)-bisdechlorogeodin with sulochrin oxidase from Penicillium frequentans and Oospora sulphurea-ochracea
Arch. Microbiol.
131
208-211
1982
Oospora sulphurea-ochracea
brenda
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1.21.3.5 sulochrin oxidase [(-)-bisdechlorogeodin-forming]
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