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Information on EC 1.21.3.2 - columbamine oxidase

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EC Tree
     1 Oxidoreductases
         1.21 Catalysing the reaction X-H + Y-H = X-Y
             1.21.3 With oxygen as acceptor
                1.21.3.2 columbamine oxidase
IUBMB Comments
An iron protein. Oxidation of the O-methoxyphenol structure forms the methylenedioxy group of berberine.
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The expected taxonomic range for this enzyme is: Berberis stolonifera
Synonyms
berberine synthase, EC 1.1.3.26, synthase, berberine, more
REACTION
REACTION DIAGRAM
COMMENTARY hide
ORGANISM
UNIPROT
LITERATURE
2 columbamine + O2 = 2 berberine + 2 H2O
show the reaction diagram
oxidation of the O-methoxyphenol structure forms the methylenedioxy group of berberine
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