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Information on EC 1.14.15.23 - chloroacetanilide N-alkylformylase

for references in articles please use BRENDA:EC1.14.15.23
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IUBMB Comments
The enzyme, characterized from the bacterium Sphingomonas sp. DC-6, initiates the degradation of several chloroacetanilide herbicides, including alachlor, acetochlor, and butachlor. The enzyme is a Rieske non-heme iron oxygenase, and requires a ferredoxin and EC 1.18.1.3, ferredoxin---NAD+ reductase, for activity.
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The expected taxonomic range for this enzyme is: Sphingomonadaceae
Reaction Schemes
+
2
reduced ferredoxin [iron-sulfur] cluster
+
=
+
+
2
oxidized ferredoxin [iron-sulfur] cluster
+
Synonyms
cndA, more
REACTION
REACTION DIAGRAM
COMMENTARY hide
ORGANISM
UNIPROT
LITERATURE
butachlor + 2 reduced ferredoxin [iron-sulfur] cluster + O2 = 2-chloro-N-(2,6-diethylphenyl)acetamide + butyl formate + 2 oxidized ferredoxin [iron-sulfur] cluster + H2O
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