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Information on EC 1.14.14.36 - tyrosine N-monooxygenase

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IUBMB Comments
A cytochrome P-450 (heme-thiolate) protein. The enzyme from Sorghum is involved in the biosynthesis of the cyanogenic glucoside dhurrin. In Sinapis alba (white mustard) the enzyme is involved in the biosynthesis of the glucosinolate sinalbin.
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Word Map
The enzyme appears in viruses and cellular organisms
Synonyms
cyp79a1, cyp79, cytochrome p450tyr, cytochrome p-450tyr, p450tyr, tyrosine n-hydroxylase, more
REACTION
REACTION DIAGRAM
COMMENTARY hide
ORGANISM
UNIPROT
LITERATURE
L-tyrosine + 2 O2 + 2 [reduced NADPH-hemoprotein reductase] = (E)-[4-hydroxyphenylacetaldehyde oxime] + 2 [oxidized NADPH-hemoprotein reductase] + CO2 + 3 H2O
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overall reaction
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L-tyrosine + O2 + [reduced NADPH-hemoprotein reductase] = N-hydroxy-L-tyrosine + [oxidized NADPH-hemoprotein reductase] + H2O
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(1a)
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N,N-dihydroxy-L-tyrosine = (E)-[4-hydroxyphenylacetaldehyde oxime] + CO2 + H2O
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(1c)
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N-hydroxy-L-tyrosine + O2 + [reduced NADPH-hemoprotein reductase] = N,N-dihydroxy-L-tyrosine + [oxidized NADPH-hemoprotein reductase] + H2O
show the reaction diagram
(1b)
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