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Information on EC 1.14.14.169 - eupatolide synthase

for references in articles please use BRENDA:EC1.14.14.169

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IUBMB Comments

A cytochrome P-450 (heme-thiolate) protein from the plant Helianthus annuus (common sunflower).

The expected taxonomic range for this enzyme is: Helianthus annuus

Synonyms
cyp71dd6, more

REACTION
REACTION DIAGRAM
COMMENTARY hide
ORGANISM
UNIPROT
LITERATURE
6alpha,8beta-dihydroxygermacra-1(10),4,11(13)-trien-12-oate = eupatolide + H2O
show the reaction diagram
(1b), spontaneous
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8beta-hydroxygermacra-1(10),4,11(13)-trien-12-oate + [reduced NADPH-hemoprotein reductase] + O2 = 6alpha,8beta-dihydroxygermacra-1(10),4,11(13)-trien-12-oate + [oxidized NADPH-hemoprotein reductase] + H2O
show the reaction diagram
(1a)
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8beta-hydroxygermacra-1(10),4,11(13)-trien-12-oate + [reduced NADPH-hemoprotein reductase] + O2 = eupatolide + [oxidized NADPH-hemoprotein reductase] + 2 H2O
show the reaction diagram
overall reaction
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PATHWAY SOURCE
PATHWAYS
Highest Expressing Human Cell Lines
Cell Line Links Gene Links