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A cytochrome P-450 (heme thiolate) enzyme characterized from maize. The enzyme catalyses the epoxidation of dolabradiene at C-16, followed by hydroxylation at C-3.
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The expected taxonomic range for this enzyme is: Zea mays
15,16-epoxydolabrene + O2 + [reduced NADPH-hemoprotein reductase] = 3beta-hydroxy-15,16-epoxydolabrene + H2O + [oxidized NADPH-hemoprotein reductase]
dolabradiene + O2 + [reduced NADPH-hemoprotein reductase] = 15,16-epoxydolabrene + H2O + [oxidized NADPH-hemoprotein reductase]
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