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IUBMB Comments The enzyme from the bacterium Xanthomonas oryzae is able to reduce enantioselectively only one of the two carbonyl groups of benzil to give optically active (R)-benzoin.
The expected taxonomic range for this enzyme is: Xanthomonas oryzae
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(R)-benzoin + NADP+ = benzil + NADPH + H+
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(R)-benzoin:NADP+ oxidoreductase
The enzyme from the bacterium Xanthomonas oryzae is able to reduce enantioselectively only one of the two carbonyl groups of benzil to give optically active (R)-benzoin.
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(R)-benzoin + NADP+
benzil + NADPH + H+
(R)-benzoin + NADP+
benzil + NADPH + H+
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r
(R)-benzoin + NADP+
benzil + NADPH + H+
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complete transformation of benzil to (R)-benzoin in cells within 3 days after feeding without formation of 1,2-diphenylethanediol as a side product
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r
(R)-benzoin + NADP+
benzil + NADPH + H+
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r
(R)-benzoin + NADP+
benzil + NADPH + H+
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complete transformation of benzil to (R)-benzoin in cells within 3 days after feeding without formation of 1,2-diphenylethanediol as a side product
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r
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(R)-benzoin + NADP+
benzil + NADPH + H+
(R)-benzoin + NADP+
benzil + NADPH + H+
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complete transformation of benzil to (R)-benzoin in cells within 3 days after feeding without formation of 1,2-diphenylethanediol as a side product
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r
(R)-benzoin + NADP+
benzil + NADPH + H+
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complete transformation of benzil to (R)-benzoin in cells within 3 days after feeding without formation of 1,2-diphenylethanediol as a side product
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r
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brenda
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brenda
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synthesis
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the enzyme can be used for the highly enantioselective reduction of benzil to produce (R)-benzoin
synthesis
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the enzyme can be used for the highly enantioselective reduction of benzil to produce (R)-benzoin
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Konoshi, J.; Ohta, H.; Tuchihashu, G.
Asymmetric reduction of benzil to benzoin catalyzed by the enzyme system of a microorganism
Chem. Lett.
14
1111-1112
1985
Xanthomonas oryzae, Xanthomonas oryzae IAM 1657
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brenda
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Enzyme Nomenclature
1.1.1.321 benzil reductase [(R)-benzoin forming]
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