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Oxidation on the 4-position of the hexose moiety takes place only while the substrate is bound to another enzyme that catalyses epimerization at C-3 and C-5.
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The expected taxonomic range for this enzyme is: Escherichia coli
dehydrogenase, thymidine diphospho-6-deoxy-L-talose, dTDP-6-deoxy-L-talose dehydrogenase (4-reductase), TDP-6-deoxy-L-talose dehydrogenase, thymidine diphospho-6-deoxy-L-talose dehydrogenase, more
dTDP-6-deoxy-beta-L-talose + NADP+ = dTDP-4-dehydro-beta-L-rhamnose + NADPH + H+
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