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Literature summary for 5.5.1.8 extracted from

  • Croteau, R.B.; Shaskus, J.J.; Renstrom, B.; Felton, N.M.; Cane, D.E.; Saito, A.; Chang, C.
    Mechanism of the pyrophosphate migration in the enzymatic cyclization of geranyl and linalyl pyrophosphate to (+)- and (-)-bornyl pyrophosphate (1985), Biochemistry, 24, 7077-7085.
    View publication on PubMed

Organism

Organism UniProt Comment Textmining
Salvia officinalis
-
-
-
Tanacetum vulgare
-
-
-

Reaction

Reaction Comment Organism Reaction ID
geranyl diphosphate = (+)-bornyl diphosphate mechanism Salvia officinalis
geranyl diphosphate = (+)-bornyl diphosphate mechanism Tanacetum vulgare
geranyl diphosphate = (+)-bornyl diphosphate linalyl diphosphate is an intermediate Salvia officinalis
geranyl diphosphate = (+)-bornyl diphosphate linalyl diphosphate is an intermediate Tanacetum vulgare
geranyl diphosphate = (+)-bornyl diphosphate solely the diphosphate ester oxygen of geranyl diphosphate is involved in all the critical bonding processes in the coupled isomerization-cyclization Salvia officinalis
geranyl diphosphate = (+)-bornyl diphosphate solely the diphosphate ester oxygen of geranyl diphosphate is involved in all the critical bonding processes in the coupled isomerization-cyclization Tanacetum vulgare

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
Geranyl diphosphate
-
Salvia officinalis (+)-Bornyl-diphosphate
-
?
Geranyl diphosphate
-
Tanacetum vulgare (-)-Bornyl-diphosphate
-
?